4-aza-1-azoniabicyclo[2.2.2]octane dihydrogenphosphite

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Abstract

The title compound, C6H13N+.H2PO3-, contains monoprotonated 4-aza-1-azoniabicyclo[2.2.2] octane (dabconium, C6H13N+) cations and dihydrogenphosphite (H2PO3-) anions. The H2PO3- units are linked into a polymeric chain by P-O-H...O-P hydrogen bonds in the [100] direction. The dabconium cations are pendant to the dihydrogenphosphite chains by way of N-H...O hydrogen bonds and possible C-H...O interactions. The chains are crosslinked by means of van der Waals forces.

Original languageEnglish
Number of pages3
JournalActa Crystallographica Section E: Structure Reports Online
Volume59
DOIs
Publication statusPublished - 2003

Keywords

  • PHOSPHITE

Cite this

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title = "4-aza-1-azoniabicyclo[2.2.2]octane dihydrogenphosphite",
abstract = "The title compound, C6H13N+.H2PO3-, contains monoprotonated 4-aza-1-azoniabicyclo[2.2.2] octane (dabconium, C6H13N+) cations and dihydrogenphosphite (H2PO3-) anions. The H2PO3- units are linked into a polymeric chain by P-O-H...O-P hydrogen bonds in the [100] direction. The dabconium cations are pendant to the dihydrogenphosphite chains by way of N-H...O hydrogen bonds and possible C-H...O interactions. The chains are crosslinked by means of van der Waals forces.",
keywords = "PHOSPHITE",
author = "Harrison, {W T A}",
year = "2003",
doi = "10.1107/S1600536803018130",
language = "English",
volume = "59",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - 4-aza-1-azoniabicyclo[2.2.2]octane dihydrogenphosphite

AU - Harrison, W T A

PY - 2003

Y1 - 2003

N2 - The title compound, C6H13N+.H2PO3-, contains monoprotonated 4-aza-1-azoniabicyclo[2.2.2] octane (dabconium, C6H13N+) cations and dihydrogenphosphite (H2PO3-) anions. The H2PO3- units are linked into a polymeric chain by P-O-H...O-P hydrogen bonds in the [100] direction. The dabconium cations are pendant to the dihydrogenphosphite chains by way of N-H...O hydrogen bonds and possible C-H...O interactions. The chains are crosslinked by means of van der Waals forces.

AB - The title compound, C6H13N+.H2PO3-, contains monoprotonated 4-aza-1-azoniabicyclo[2.2.2] octane (dabconium, C6H13N+) cations and dihydrogenphosphite (H2PO3-) anions. The H2PO3- units are linked into a polymeric chain by P-O-H...O-P hydrogen bonds in the [100] direction. The dabconium cations are pendant to the dihydrogenphosphite chains by way of N-H...O hydrogen bonds and possible C-H...O interactions. The chains are crosslinked by means of van der Waals forces.

KW - PHOSPHITE

U2 - 10.1107/S1600536803018130

DO - 10.1107/S1600536803018130

M3 - Article

VL - 59

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

ER -