Abstract
In the crystal structures of (4-nitrophenylsulfanylmethyl)triphenylstannane, [Sn(C6H5)(3) (C7H6NO2S)], (I), and (4-nitrophenylsulfonylmethyl)triphenylstannane, [Sn(C6H5)(3) (C7H6NO4S)], (II), the molecules are linked by paired C-H...O hydrogen bonds into centrosymmetric dimers which combine to form sheets. In (I), two such dimers form to give R-2(2) (10) and R-2(2) (24) rings. In (II), similar dimers form, here with R-2(2) (10) and R-2(2) (18) rings, but with an additional dimer due to the presence of the sulfone group, giving R-2(2) (10) rings. In both structures, C-H...pi interactions lead to a doubling of the width of the sheets.
Formula: [Sn(C6H5)3(C7H6NO2S)] and [Sn(C6H5)3(C7H6NO4S)]
Original language | English |
---|---|
Pages (from-to) | m413-m417 |
Number of pages | 5 |
Journal | Acta Crystallographica Section C, Crystal Structure Communications |
Volume | 58 |
Issue number | 7 |
DOIs | |
Publication status | Published - Jul 2002 |
Keywords
- O Hydrogen-bonds
- substituted organotin compounds
- molecular-structure
- disulfide
- crystal