(4-Nitrophenylsulfanylmethyl)triphenylstannane and (4-nitrophenylsulfonylmethyl)triphenylstannane: R22(X) rings (X is 10, 18 or 24) and C-H...p interactions

Jan Skakle, J. L. Wardell, S. M. S. V. Wardell

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Abstract

In the crystal structures of (4-nitrophenylsulfanylmethyl)triphenylstannane, [Sn(C6H5)(3) (C7H6NO2S)], (I), and (4-nitrophenylsulfonylmethyl)triphenylstannane, [Sn(C6H5)(3) (C7H6NO4S)], (II), the molecules are linked by paired C-H...O hydrogen bonds into centrosymmetric dimers which combine to form sheets. In (I), two such dimers form to give R-2(2) (10) and R-2(2) (24) rings. In (II), similar dimers form, here with R-2(2) (10) and R-2(2) (18) rings, but with an additional dimer due to the presence of the sulfone group, giving R-2(2) (10) rings. In both structures, C-H...pi interactions lead to a doubling of the width of the sheets.

Formula: [Sn(C6H5)3(C7H6NO2S)] and [Sn(C6H5)3(C7H6NO4S)]

Original languageEnglish
Pages (from-to)m413-m417
Number of pages5
JournalActa Crystallographica Section C, Crystal Structure Communications
Volume58
Issue number7
DOIs
Publication statusPublished - Jul 2002

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Sulfones
Dimers
Hydrogen
Hydrogen bonds
Crystal structure
Molecules

Keywords

  • O Hydrogen-bonds
  • substituted organotin compounds
  • molecular-structure
  • disulfide
  • crystal

Cite this

@article{2006194f55184a1489aa0522b804d28e,
title = "(4-Nitrophenylsulfanylmethyl)triphenylstannane and (4-nitrophenylsulfonylmethyl)triphenylstannane: R22(X) rings (X is 10, 18 or 24) and C-H...p interactions",
abstract = "In the crystal structures of (4-nitrophenylsulfanylmethyl)triphenylstannane, [Sn(C6H5)(3) (C7H6NO2S)], (I), and (4-nitrophenylsulfonylmethyl)triphenylstannane, [Sn(C6H5)(3) (C7H6NO4S)], (II), the molecules are linked by paired C-H...O hydrogen bonds into centrosymmetric dimers which combine to form sheets. In (I), two such dimers form to give R-2(2) (10) and R-2(2) (24) rings. In (II), similar dimers form, here with R-2(2) (10) and R-2(2) (18) rings, but with an additional dimer due to the presence of the sulfone group, giving R-2(2) (10) rings. In both structures, C-H...pi interactions lead to a doubling of the width of the sheets. Formula: [Sn(C6H5)3(C7H6NO2S)] and [Sn(C6H5)3(C7H6NO4S)]",
keywords = "O Hydrogen-bonds, substituted organotin compounds, molecular-structure, disulfide, crystal",
author = "Jan Skakle and Wardell, {J. L.} and Wardell, {S. M. S. V.}",
year = "2002",
month = "7",
doi = "10.1107/S0108270102010375",
language = "English",
volume = "58",
pages = "m413--m417",
journal = "Acta Crystallographica Section C, Crystal Structure Communications",
issn = "0108-2701",
publisher = "Wiley-Blackwell",
number = "7",

}

TY - JOUR

T1 - (4-Nitrophenylsulfanylmethyl)triphenylstannane and (4-nitrophenylsulfonylmethyl)triphenylstannane: R22(X) rings (X is 10, 18 or 24) and C-H...p interactions

AU - Skakle, Jan

AU - Wardell, J. L.

AU - Wardell, S. M. S. V.

PY - 2002/7

Y1 - 2002/7

N2 - In the crystal structures of (4-nitrophenylsulfanylmethyl)triphenylstannane, [Sn(C6H5)(3) (C7H6NO2S)], (I), and (4-nitrophenylsulfonylmethyl)triphenylstannane, [Sn(C6H5)(3) (C7H6NO4S)], (II), the molecules are linked by paired C-H...O hydrogen bonds into centrosymmetric dimers which combine to form sheets. In (I), two such dimers form to give R-2(2) (10) and R-2(2) (24) rings. In (II), similar dimers form, here with R-2(2) (10) and R-2(2) (18) rings, but with an additional dimer due to the presence of the sulfone group, giving R-2(2) (10) rings. In both structures, C-H...pi interactions lead to a doubling of the width of the sheets. Formula: [Sn(C6H5)3(C7H6NO2S)] and [Sn(C6H5)3(C7H6NO4S)]

AB - In the crystal structures of (4-nitrophenylsulfanylmethyl)triphenylstannane, [Sn(C6H5)(3) (C7H6NO2S)], (I), and (4-nitrophenylsulfonylmethyl)triphenylstannane, [Sn(C6H5)(3) (C7H6NO4S)], (II), the molecules are linked by paired C-H...O hydrogen bonds into centrosymmetric dimers which combine to form sheets. In (I), two such dimers form to give R-2(2) (10) and R-2(2) (24) rings. In (II), similar dimers form, here with R-2(2) (10) and R-2(2) (18) rings, but with an additional dimer due to the presence of the sulfone group, giving R-2(2) (10) rings. In both structures, C-H...pi interactions lead to a doubling of the width of the sheets. Formula: [Sn(C6H5)3(C7H6NO2S)] and [Sn(C6H5)3(C7H6NO4S)]

KW - O Hydrogen-bonds

KW - substituted organotin compounds

KW - molecular-structure

KW - disulfide

KW - crystal

U2 - 10.1107/S0108270102010375

DO - 10.1107/S0108270102010375

M3 - Article

VL - 58

SP - m413-m417

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

SN - 0108-2701

IS - 7

ER -