TY - JOUR
T1 - (4-Nitrophenylsulfinyl)acetic acid, a three dimensional hydrogen-bonded framework built from a combination of two-centre O–H and C–H hydrogen bonds and a three-centre C–H 2 hydrogen bond
AU - Glidewell, C
AU - Low, J N
AU - Skakle, J M S
AU - Wardell, J L
PY - 2003
Y1 - 2003
N2 - Molecules of the title compound, C8H7NO5S, are linked into sheets by a combination of two-centre hydrogen bonds, one of type O-H...O [H...O = 1.81 Angstrom, O...O = 2.648 (2) Angstrom and O-H...O = 173degrees] and three of type C-H...O [H...O = 2.40-2.48 Angstrom, C...O = 3.206 (3)-3.391 (3) Angstrom and C-H ... O = 131-160degrees]. These sheets are linked by an unusual three-centre C-H...(O)(2) hydrogen bond [H...O = 2.46 and 2.56 Angstrom, C...O = 3.289 (3) and 3.351 (3) Angstrom, and C-H...O = 141 and 137degrees], in which the two acceptors are carboxyl and sulfoxide O atoms.
AB - Molecules of the title compound, C8H7NO5S, are linked into sheets by a combination of two-centre hydrogen bonds, one of type O-H...O [H...O = 1.81 Angstrom, O...O = 2.648 (2) Angstrom and O-H...O = 173degrees] and three of type C-H...O [H...O = 2.40-2.48 Angstrom, C...O = 3.206 (3)-3.391 (3) Angstrom and C-H ... O = 131-160degrees]. These sheets are linked by an unusual three-centre C-H...(O)(2) hydrogen bond [H...O = 2.46 and 2.56 Angstrom, C...O = 3.289 (3) and 3.351 (3) Angstrom, and C-H...O = 141 and 137degrees], in which the two acceptors are carboxyl and sulfoxide O atoms.
U2 - 10.1107/S0108270103001860
DO - 10.1107/S0108270103001860
M3 - Article
VL - C59
SP - o124-o126
JO - Acta Crystallographica Section C, Crystal Structure Communications
JF - Acta Crystallographica Section C, Crystal Structure Communications
SN - 0108-2701
ER -