4,4-Bis(4-iodophenylaminomethyl)-azoxybenzene: hydrogen-bonded sheets built from C-H center dot center dot center dot O and C-H center dot center dot center dot pi(arene) hydrogen bonds

C Glidewell, J N Low, J M S Skakle, J L Wardell

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Abstract

Borohydride reduction of N-(4-nitrobenzylidene)-4-iodoaniline has yielded the title compound, 1,2- bis[4-(4-iodophenylaminomethyl) phenyl] diazene 1-oxide, C26H22I2N4O. The molecules lie across centres of inversion in P2(1)/c, with the azoxy O atom disordered over two sites, each having an occupancy of 0.5. The molecules are linked into sheets by a combination of C-H...O and C-H...pi(arene) hydrogen bonds.

Original languageEnglish
Pages (from-to)o207-o209
Number of pages3
JournalActa Crystallographica Section C, Crystal Structure Communications
VolumeC59
Issue number4
DOIs
Publication statusPublished - 2003

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Borohydrides
Oxides
Hydrogen
Hydrogen bonds
Molecules
Atoms
fenazox
4-iodoaniline
diazene

Cite this

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title = "4,4-Bis(4-iodophenylaminomethyl)-azoxybenzene: hydrogen-bonded sheets built from C-H center dot center dot center dot O and C-H center dot center dot center dot pi(arene) hydrogen bonds",
abstract = "Borohydride reduction of N-(4-nitrobenzylidene)-4-iodoaniline has yielded the title compound, 1,2- bis[4-(4-iodophenylaminomethyl) phenyl] diazene 1-oxide, C26H22I2N4O. The molecules lie across centres of inversion in P2(1)/c, with the azoxy O atom disordered over two sites, each having an occupancy of 0.5. The molecules are linked into sheets by a combination of C-H...O and C-H...pi(arene) hydrogen bonds.",
author = "C Glidewell and Low, {J N} and Skakle, {J M S} and Wardell, {J L}",
year = "2003",
doi = "10.1107/S0108270103005511",
language = "English",
volume = "C59",
pages = "o207--o209",
journal = "Acta Crystallographica Section C, Crystal Structure Communications",
issn = "0108-2701",
publisher = "Wiley-Blackwell",
number = "4",

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TY - JOUR

T1 - 4,4-Bis(4-iodophenylaminomethyl)-azoxybenzene: hydrogen-bonded sheets built from C-H center dot center dot center dot O and C-H center dot center dot center dot pi(arene) hydrogen bonds

AU - Glidewell, C

AU - Low, J N

AU - Skakle, J M S

AU - Wardell, J L

PY - 2003

Y1 - 2003

N2 - Borohydride reduction of N-(4-nitrobenzylidene)-4-iodoaniline has yielded the title compound, 1,2- bis[4-(4-iodophenylaminomethyl) phenyl] diazene 1-oxide, C26H22I2N4O. The molecules lie across centres of inversion in P2(1)/c, with the azoxy O atom disordered over two sites, each having an occupancy of 0.5. The molecules are linked into sheets by a combination of C-H...O and C-H...pi(arene) hydrogen bonds.

AB - Borohydride reduction of N-(4-nitrobenzylidene)-4-iodoaniline has yielded the title compound, 1,2- bis[4-(4-iodophenylaminomethyl) phenyl] diazene 1-oxide, C26H22I2N4O. The molecules lie across centres of inversion in P2(1)/c, with the azoxy O atom disordered over two sites, each having an occupancy of 0.5. The molecules are linked into sheets by a combination of C-H...O and C-H...pi(arene) hydrogen bonds.

U2 - 10.1107/S0108270103005511

DO - 10.1107/S0108270103005511

M3 - Article

VL - C59

SP - o207-o209

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

SN - 0108-2701

IS - 4

ER -