(4S,5S)-2,2-dimethyl-4,5-bis(3-methyl-2-thioxo-2,3-dihydro-1H-imidazol-1-ylmethyl)-1,3-dioxolane

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

In the chiral title compound, C15H22N4O2S2, there are two molecules in the asymmetric unit with distinctly different conformations, as quantified by torsion angles. The dihedral angles between the thioimidazole rings are 81.59 (5) and 67.04 (4)degrees. One molecule exhibits local twofold rotation symmetry, while the other displays no local symmetry. Intermolecular C-H center dot center dot center dot O and C-H center dot center dot center dot S interactions are observed.

Original languageEnglish
Article numbero58
JournalActa Crystallographica Section E: Structure Reports Online
Volume64
Issue number1
DOIs
Publication statusPublished - Jan 2008

Cite this

@article{d0f32afb48b248518fc6c11a63b8248c,
title = "(4S,5S)-2,2-dimethyl-4,5-bis(3-methyl-2-thioxo-2,3-dihydro-1H-imidazol-1-ylmethyl)-1,3-dioxolane",
abstract = "In the chiral title compound, C15H22N4O2S2, there are two molecules in the asymmetric unit with distinctly different conformations, as quantified by torsion angles. The dihedral angles between the thioimidazole rings are 81.59 (5) and 67.04 (4)degrees. One molecule exhibits local twofold rotation symmetry, while the other displays no local symmetry. Intermolecular C-H center dot center dot center dot O and C-H center dot center dot center dot S interactions are observed.",
author = "Colin Marshall and Harrison, {William T. A.}",
year = "2008",
month = "1",
doi = "10.1107/S1600536807055948",
language = "English",
volume = "64",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "1",

}

TY - JOUR

T1 - (4S,5S)-2,2-dimethyl-4,5-bis(3-methyl-2-thioxo-2,3-dihydro-1H-imidazol-1-ylmethyl)-1,3-dioxolane

AU - Marshall, Colin

AU - Harrison, William T. A.

PY - 2008/1

Y1 - 2008/1

N2 - In the chiral title compound, C15H22N4O2S2, there are two molecules in the asymmetric unit with distinctly different conformations, as quantified by torsion angles. The dihedral angles between the thioimidazole rings are 81.59 (5) and 67.04 (4)degrees. One molecule exhibits local twofold rotation symmetry, while the other displays no local symmetry. Intermolecular C-H center dot center dot center dot O and C-H center dot center dot center dot S interactions are observed.

AB - In the chiral title compound, C15H22N4O2S2, there are two molecules in the asymmetric unit with distinctly different conformations, as quantified by torsion angles. The dihedral angles between the thioimidazole rings are 81.59 (5) and 67.04 (4)degrees. One molecule exhibits local twofold rotation symmetry, while the other displays no local symmetry. Intermolecular C-H center dot center dot center dot O and C-H center dot center dot center dot S interactions are observed.

U2 - 10.1107/S1600536807055948

DO - 10.1107/S1600536807055948

M3 - Article

VL - 64

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 1

M1 - o58

ER -