TY - JOUR
T1 - (4Z)-1-Methyl-4-[(2E)-2-(4-methylbenzyl-idene)hydrazin-1-ylidene]-3, 4-dihydro-1 H-2λ6,1-benzothiazine-2,2-dione
AU - Shafiq, Muhammad
AU - Harrison, William Thomas Alexander
AU - Khan, Islam Ullah
AU - Ejaz, null
PY - 2012/10
Y1 - 2012/10
N2 - In the title compound, C17H17N3O2S, the dihedral angle between the aromatic rings is 6.3 (5)° and the C=N - N=C group is statistically planar [torsion angle = 179.8 (8)°]. The conformation of the thiazine ring is an envelope, with the S atom displaced by 0.823 (9) Å from the mean plane of the other five atoms (r.m.s. deviation = 0.012 Å). In the crystal, C - H···O interactions link the molecules into C(5) chains propagating along [101]. The chains are consolidated by weak aromatic φ-φ stacking between the benzene and toluene rings [centroid-to-centroid separation = 3.826 (5) Å and interplanar angle = 6.3 (4)°].
AB - In the title compound, C17H17N3O2S, the dihedral angle between the aromatic rings is 6.3 (5)° and the C=N - N=C group is statistically planar [torsion angle = 179.8 (8)°]. The conformation of the thiazine ring is an envelope, with the S atom displaced by 0.823 (9) Å from the mean plane of the other five atoms (r.m.s. deviation = 0.012 Å). In the crystal, C - H···O interactions link the molecules into C(5) chains propagating along [101]. The chains are consolidated by weak aromatic φ-φ stacking between the benzene and toluene rings [centroid-to-centroid separation = 3.826 (5) Å and interplanar angle = 6.3 (4)°].
UR - http://www.scopus.com/inward/record.url?scp=84867211242&partnerID=8YFLogxK
U2 - 10.1107/S1600536812039529
DO - 10.1107/S1600536812039529
M3 - Article
AN - SCOPUS:84867211242
VL - E68
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
M1 - o2971
ER -