TY - JOUR
T1 - 6-Bromo-4-[2-(4-fluorobenzylidene)-hydrazin-1-ylidene]-1-methyl-3, 4-dihydro-1H-2λ6,1-benzothiazine-2,2-dione
AU - Shafiq, Muhammad
AU - Khan, Islam Ullah
AU - Harrison, William T.A.
AU - Hussain, Ajaz
AU - Ashraf, Hina
PY - 2012/10/1
Y1 - 2012/10/1
N2 - In the title compound, C16H13BrFN3O 2S, the dihedral angle between the aromatic rings is 2.55 (19)° and the C=N - N=C torsion angle is 178.9 (3)°. The conformation of the thiazine ring is an envelope, with the S atom displaced by - 0.811 (3)Å from the mean plane of the other five atoms (r.m.s. deviation = 0.042Å). In the crystal, C - H···O interactions link the molecules and weak aromatic π-π stacking between the fluorobenzene and bromobenzene rings [centroid-centroid separation = 3.720 (2)Å and interplanar angle = 2.6 (2)°] is also observed.
AB - In the title compound, C16H13BrFN3O 2S, the dihedral angle between the aromatic rings is 2.55 (19)° and the C=N - N=C torsion angle is 178.9 (3)°. The conformation of the thiazine ring is an envelope, with the S atom displaced by - 0.811 (3)Å from the mean plane of the other five atoms (r.m.s. deviation = 0.042Å). In the crystal, C - H···O interactions link the molecules and weak aromatic π-π stacking between the fluorobenzene and bromobenzene rings [centroid-centroid separation = 3.720 (2)Å and interplanar angle = 2.6 (2)°] is also observed.
UR - http://www.scopus.com/inward/record.url?scp=84867210936&partnerID=8YFLogxK
U2 - 10.1107/S1600536812037403
DO - 10.1107/S1600536812037403
M3 - Article
AN - SCOPUS:84867210936
VL - 68
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 10
M1 - o2851
ER -