Barsilowsky's base and Perkin's base: two products from the oxidation of p-toluidine

M. John Plater; William T. A. Harrison

doi:10.3184/174751914X13995700264041

Barsilowsky's base and Perkin's base: two products from the oxidation of p-toluidine

M. John Plater, William T. A. Harrison

Chemistry

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Abstract

The oxidation of p-toluidine in H+/H2O can give mainly a tetramer, a trimer, or a mixture of both. The outcome is dependent upon the oxidant, the pH and the concentration ofp-toluidine. Both the trimer and tetramer are definitively characterised by X-ray single crystal structure determination.

Original language	English
Pages (from-to)	351-355
Number of pages	5
Journal	Journal of Chemical Research
Volume	38
Issue number	6
DOIs	https://doi.org/10.3184/174751914X13995700264041
Publication status	Published - 1 Jun 2014

Keywords

Barsilowsky's base
p-toluidine
Perkins's base
potassium dichromate
potassium permanganate

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10.3184/174751914X13995700264041

JCR Barsilowsky vs Perkin REVISED MS
This is the author's accepted manuscript of an article published in the Journal of Chemical Research
Accepted author manuscript, 310 KB

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title = "Barsilowsky's base and Perkin's base: two products from the oxidation of p-toluidine ",

abstract = "The oxidation of p-toluidine in H+/H2O can give mainly a tetramer, a trimer, or a mixture of both. The outcome is dependent upon the oxidant, the pH and the concentration ofp-toluidine. Both the trimer and tetramer are definitively characterised by X-ray single crystal structure determination. ",

keywords = "Barsilowsky's base, p-toluidine, Perkins's base, potassium dichromate, potassium permanganate",

author = "Plater, {M. John} and Harrison, {William T. A.}",

note = "Acknowledgements We are grateful to the UK EPSRC national mass spectrometry service center for mass spectra. ",

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AU - Plater, M. John

AU - Harrison, William T. A.

N1 - Acknowledgements We are grateful to the UK EPSRC national mass spectrometry service center for mass spectra.

PY - 2014/6/1

Y1 - 2014/6/1

N2 - The oxidation of p-toluidine in H+/H2O can give mainly a tetramer, a trimer, or a mixture of both. The outcome is dependent upon the oxidant, the pH and the concentration ofp-toluidine. Both the trimer and tetramer are definitively characterised by X-ray single crystal structure determination.

AB - The oxidation of p-toluidine in H+/H2O can give mainly a tetramer, a trimer, or a mixture of both. The outcome is dependent upon the oxidant, the pH and the concentration ofp-toluidine. Both the trimer and tetramer are definitively characterised by X-ray single crystal structure determination.

KW - Barsilowsky's base

KW - p-toluidine

KW - Perkins's base

KW - potassium dichromate

KW - potassium permanganate

U2 - 10.3184/174751914X13995700264041

DO - 10.3184/174751914X13995700264041

M3 - Article

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SP - 351

EP - 355

JO - Journal of Chemical Research

JF - Journal of Chemical Research

SN - 0308-2342

IS - 6

ER -

Barsilowsky's base and Perkin's base: two products from the oxidation of p-toluidine

Abstract

Keywords

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