Barsilowsky's base and Perkin's base

two products from the oxidation of p-toluidine

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3 Citations (Scopus)
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Abstract

The oxidation of p-toluidine in H+/H2O can give mainly a tetramer, a trimer, or a mixture of both. The outcome is dependent upon the oxidant, the pH and the concentration ofp-toluidine. Both the trimer and tetramer are definitively characterised by X-ray single crystal structure determination.
Original languageEnglish
Pages (from-to)351-355
Number of pages5
JournalJournal of Chemical Research
Volume38
Issue number6
DOIs
Publication statusPublished - 1 Jun 2014

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Toluidines
Oxidants
Crystal structure
Single crystals
X rays
Oxidation
4-toluidine

Keywords

  • Barsilowsky's base
  • p-toluidine
  • Perkins's base
  • potassium dichromate
  • potassium permanganate

Cite this

@article{b99e33da0ed543b4843f7f6a2be205ad,
title = "Barsilowsky's base and Perkin's base: two products from the oxidation of p-toluidine",
abstract = "The oxidation of p-toluidine in H+/H2O can give mainly a tetramer, a trimer, or a mixture of both. The outcome is dependent upon the oxidant, the pH and the concentration ofp-toluidine. Both the trimer and tetramer are definitively characterised by X-ray single crystal structure determination.",
keywords = "Barsilowsky's base, p-toluidine, Perkins's base, potassium dichromate, potassium permanganate",
author = "Plater, {M. John} and Harrison, {William T. A.}",
note = "Acknowledgements We are grateful to the UK EPSRC national mass spectrometry service center for mass spectra.",
year = "2014",
month = "6",
day = "1",
doi = "10.3184/174751914X13995700264041",
language = "English",
volume = "38",
pages = "351--355",
journal = "Journal of Chemical Research",
issn = "0308-2342",
publisher = "Science Reviews Ltd",
number = "6",

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TY - JOUR

T1 - Barsilowsky's base and Perkin's base

T2 - two products from the oxidation of p-toluidine

AU - Plater, M. John

AU - Harrison, William T. A.

N1 - Acknowledgements We are grateful to the UK EPSRC national mass spectrometry service center for mass spectra.

PY - 2014/6/1

Y1 - 2014/6/1

N2 - The oxidation of p-toluidine in H+/H2O can give mainly a tetramer, a trimer, or a mixture of both. The outcome is dependent upon the oxidant, the pH and the concentration ofp-toluidine. Both the trimer and tetramer are definitively characterised by X-ray single crystal structure determination.

AB - The oxidation of p-toluidine in H+/H2O can give mainly a tetramer, a trimer, or a mixture of both. The outcome is dependent upon the oxidant, the pH and the concentration ofp-toluidine. Both the trimer and tetramer are definitively characterised by X-ray single crystal structure determination.

KW - Barsilowsky's base

KW - p-toluidine

KW - Perkins's base

KW - potassium dichromate

KW - potassium permanganate

U2 - 10.3184/174751914X13995700264041

DO - 10.3184/174751914X13995700264041

M3 - Article

VL - 38

SP - 351

EP - 355

JO - Journal of Chemical Research

JF - Journal of Chemical Research

SN - 0308-2342

IS - 6

ER -