Barsilowsky's base and Perkin's base: two products from the oxidation of p-toluidine

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Abstract

The oxidation of p-toluidine in H+/H2O can give mainly a tetramer, a trimer, or a mixture of both. The outcome is dependent upon the oxidant, the pH and the concentration ofp-toluidine. Both the trimer and tetramer are definitively characterised by X-ray single crystal structure determination.
Original languageEnglish
Pages (from-to)351-355
Number of pages5
JournalJournal of Chemical Research
Volume38
Issue number6
DOIs
Publication statusPublished - 1 Jun 2014

Keywords

  • Barsilowsky's base
  • p-toluidine
  • Perkins's base
  • potassium dichromate
  • potassium permanganate

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