C4N3OH7 center dot Zn(H2O)HPO4, a neutral zincophosphate cluster

I  Macdonald; W T A  Harrison

doi:10.1021/ic025886h

C4N3OH7 center dot Zn(H2O)HPO4, a neutral zincophosphate cluster

I Macdonald, W T A Harrison

Chemistry

Research output: Contribution to journal › Article

26 Citations (Scopus)

Abstract

C4N3OH7.Zn(H2O)HPO4, built up from 4-rings of ZnO2(H2O)N and HPO4 tetrahedra, is the first neutral, molecular, zincophosphate cluster. The unit-cell packing involves numerous O-H...O and N-H...O hydrogen bonds and pi...pi stacking interactions. Crystal data: C4N3OH7.Zn(H2O)HPO4, M-r = 292.49, triclinic, P1 (No. 2), a = 9.2956(5) Angstrom, b = 11.2077(6) Angstrom, c = 19.8319(12) Angstrom, alpha = 80,314(1)degrees, 78.829(1)degrees, gamma = 89.241 (1)degrees, V = 1997.7(2) Angstrom(3), Z = 4.

Original language	English
Pages (from-to)	6184-6186
Number of pages	3
Journal	Inorganic Chemistry
Volume	41
DOIs	https://doi.org/10.1021/ic025886h
Publication status	Published - 2002

Keywords

FRAMEWORK METAL PHOSPHATES
ZINC PHOSPHATES
HYDROTHERMAL SYNTHESIS
COMPLEX

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@article{efdf8afdc119445bb3d05fa20e8c65f2,

title = "C4N3OH7 center dot Zn(H2O)HPO4, a neutral zincophosphate cluster",

abstract = "C4N3OH7.Zn(H2O)HPO4, built up from 4-rings of ZnO2(H2O)N and HPO4 tetrahedra, is the first neutral, molecular, zincophosphate cluster. The unit-cell packing involves numerous O-H...O and N-H...O hydrogen bonds and pi...pi stacking interactions. Crystal data: C4N3OH7.Zn(H2O)HPO4, M-r = 292.49, triclinic, P1 (No. 2), a = 9.2956(5) Angstrom, b = 11.2077(6) Angstrom, c = 19.8319(12) Angstrom, alpha = 80,314(1)degrees, 78.829(1)degrees, gamma = 89.241 (1)degrees, V = 1997.7(2) Angstrom(3), Z = 4.",

keywords = "FRAMEWORK METAL PHOSPHATES, ZINC PHOSPHATES, HYDROTHERMAL SYNTHESIS, COMPLEX",

author = "I Macdonald and Harrison, {W T A}",

year = "2002",

doi = "10.1021/ic025886h",

language = "English",

volume = "41",

pages = "6184--6186",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

}

TY - JOUR

T1 - C4N3OH7 center dot Zn(H2O)HPO4, a neutral zincophosphate cluster

AU - Macdonald, I

AU - Harrison, W T A

PY - 2002

Y1 - 2002

N2 - C4N3OH7.Zn(H2O)HPO4, built up from 4-rings of ZnO2(H2O)N and HPO4 tetrahedra, is the first neutral, molecular, zincophosphate cluster. The unit-cell packing involves numerous O-H...O and N-H...O hydrogen bonds and pi...pi stacking interactions. Crystal data: C4N3OH7.Zn(H2O)HPO4, M-r = 292.49, triclinic, P1 (No. 2), a = 9.2956(5) Angstrom, b = 11.2077(6) Angstrom, c = 19.8319(12) Angstrom, alpha = 80,314(1)degrees, 78.829(1)degrees, gamma = 89.241 (1)degrees, V = 1997.7(2) Angstrom(3), Z = 4.

AB - C4N3OH7.Zn(H2O)HPO4, built up from 4-rings of ZnO2(H2O)N and HPO4 tetrahedra, is the first neutral, molecular, zincophosphate cluster. The unit-cell packing involves numerous O-H...O and N-H...O hydrogen bonds and pi...pi stacking interactions. Crystal data: C4N3OH7.Zn(H2O)HPO4, M-r = 292.49, triclinic, P1 (No. 2), a = 9.2956(5) Angstrom, b = 11.2077(6) Angstrom, c = 19.8319(12) Angstrom, alpha = 80,314(1)degrees, 78.829(1)degrees, gamma = 89.241 (1)degrees, V = 1997.7(2) Angstrom(3), Z = 4.

KW - FRAMEWORK METAL PHOSPHATES

KW - ZINC PHOSPHATES

KW - HYDROTHERMAL SYNTHESIS

KW - COMPLEX

U2 - 10.1021/ic025886h

DO - 10.1021/ic025886h

M3 - Article

SN - 0020-1669

VL - 41

SP - 6184

EP - 6186

JO - Inorganic Chemistry

JF - Inorganic Chemistry

ER -

C4N3OH7 center dot Zn(H2O)HPO4, a neutral zincophosphate cluster

Abstract

Keywords

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