C4N3OH7 center dot Zn(H2O)HPO4, a neutral zincophosphate cluster

I Macdonald, W T A Harrison

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

C4N3OH7.Zn(H2O)HPO4, built up from 4-rings of ZnO2(H2O)N and HPO4 tetrahedra, is the first neutral, molecular, zincophosphate cluster. The unit-cell packing involves numerous O-H...O and N-H...O hydrogen bonds and pi...pi stacking interactions. Crystal data: C4N3OH7.Zn(H2O)HPO4, M-r = 292.49, triclinic, P1 (No. 2), a = 9.2956(5) Angstrom, b = 11.2077(6) Angstrom, c = 19.8319(12) Angstrom, alpha = 80,314(1)degrees, 78.829(1)degrees, gamma = 89.241 (1)degrees, V = 1997.7(2) Angstrom(3), Z = 4.

Original languageEnglish
Pages (from-to)6184-6186
Number of pages3
JournalInorganic Chemistry
Volume41
DOIs
Publication statusPublished - 2002

Keywords

  • FRAMEWORK METAL PHOSPHATES
  • ZINC PHOSPHATES
  • HYDROTHERMAL SYNTHESIS
  • COMPLEX

Cite this

C4N3OH7 center dot Zn(H2O)HPO4, a neutral zincophosphate cluster. / Macdonald, I ; Harrison, W T A .

In: Inorganic Chemistry, Vol. 41, 2002, p. 6184-6186.

Research output: Contribution to journalArticle

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abstract = "C4N3OH7.Zn(H2O)HPO4, built up from 4-rings of ZnO2(H2O)N and HPO4 tetrahedra, is the first neutral, molecular, zincophosphate cluster. The unit-cell packing involves numerous O-H...O and N-H...O hydrogen bonds and pi...pi stacking interactions. Crystal data: C4N3OH7.Zn(H2O)HPO4, M-r = 292.49, triclinic, P1 (No. 2), a = 9.2956(5) Angstrom, b = 11.2077(6) Angstrom, c = 19.8319(12) Angstrom, alpha = 80,314(1)degrees, 78.829(1)degrees, gamma = 89.241 (1)degrees, V = 1997.7(2) Angstrom(3), Z = 4.",
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AB - C4N3OH7.Zn(H2O)HPO4, built up from 4-rings of ZnO2(H2O)N and HPO4 tetrahedra, is the first neutral, molecular, zincophosphate cluster. The unit-cell packing involves numerous O-H...O and N-H...O hydrogen bonds and pi...pi stacking interactions. Crystal data: C4N3OH7.Zn(H2O)HPO4, M-r = 292.49, triclinic, P1 (No. 2), a = 9.2956(5) Angstrom, b = 11.2077(6) Angstrom, c = 19.8319(12) Angstrom, alpha = 80,314(1)degrees, 78.829(1)degrees, gamma = 89.241 (1)degrees, V = 1997.7(2) Angstrom(3), Z = 4.

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KW - HYDROTHERMAL SYNTHESIS

KW - COMPLEX

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