(CH3CH[NH3]CH2NH3)1/2·ZnPO4, a zincophosphate analogue of aluminosilicate zeolite thomsonite

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Abstract

The synthesis and structure Of (CH3CH[NH3]CH2NH3)(1/2) . ZnPO4, an organically templated zincophosphate (ZnPO) analogue of aluminosilicate zeolite thomsonite (THO), are described. The ZnPO framework is built up from an alternating, vertex-sharing, network of ZnO4 and PO4 groups (d(av)(Zn-O) = 1.944 (8) Angstrom, d(av)(P-O) = 1.535 (9) Angstrom, theta(av)(Zn-O-P) = 130.5degrees) involving distinctive 4 = I secondary building units. The 1,2-diammonium propane cations are highly disordered in the [0 0 1] 8-ring channels. Crystal data: (CH3CH[NH3]CH2NH3)(1-2) . ZnPO4, M-r = 198.42, orthorhombic, space group Pnen (no. 52), a = 14.119 (6) Angstrom, b = 14.136 (5) Angstrom, c = 12.985 (5) Angstrom, V = 2591 (3) Angstrom(3), Z = 10, R(F) = 0.057, R-w(F) = 0.061 (for a twinned crystal). (C) 2001 Elsevier Science B.V. All rights reserved.

Original languageEnglish
Pages (from-to)187-194
Number of pages7
JournalMicroporous and Mesoporous Materials
Volume50
DOIs
Publication statusPublished - 2001

Keywords

  • fibrous zeolite
  • crystal structure
  • twinning
  • zinc
  • PHOSPHATES
  • TOPOLOGY

Cite this

@article{c57acb765cab4cabb06710a702cf4a6d,
title = "(CH3CH[NH3]CH2NH3)1/2·ZnPO4, a zincophosphate analogue of aluminosilicate zeolite thomsonite",
abstract = "The synthesis and structure Of (CH3CH[NH3]CH2NH3)(1/2) . ZnPO4, an organically templated zincophosphate (ZnPO) analogue of aluminosilicate zeolite thomsonite (THO), are described. The ZnPO framework is built up from an alternating, vertex-sharing, network of ZnO4 and PO4 groups (d(av)(Zn-O) = 1.944 (8) Angstrom, d(av)(P-O) = 1.535 (9) Angstrom, theta(av)(Zn-O-P) = 130.5degrees) involving distinctive 4 = I secondary building units. The 1,2-diammonium propane cations are highly disordered in the [0 0 1] 8-ring channels. Crystal data: (CH3CH[NH3]CH2NH3)(1-2) . ZnPO4, M-r = 198.42, orthorhombic, space group Pnen (no. 52), a = 14.119 (6) Angstrom, b = 14.136 (5) Angstrom, c = 12.985 (5) Angstrom, V = 2591 (3) Angstrom(3), Z = 10, R(F) = 0.057, R-w(F) = 0.061 (for a twinned crystal). (C) 2001 Elsevier Science B.V. All rights reserved.",
keywords = "fibrous zeolite, crystal structure, twinning, zinc, PHOSPHATES, TOPOLOGY",
author = "Ng, {H. Y.} and Harrison, {William Thomas Alexander}",
year = "2001",
doi = "10.1016/S1387-1811(01)00451-6",
language = "English",
volume = "50",
pages = "187--194",
journal = "Microporous and Mesoporous Materials",
issn = "1387-1811",
publisher = "Elsevier",

}

TY - JOUR

T1 - (CH3CH[NH3]CH2NH3)1/2·ZnPO4, a zincophosphate analogue of aluminosilicate zeolite thomsonite

AU - Ng, H. Y.

AU - Harrison, William Thomas Alexander

PY - 2001

Y1 - 2001

N2 - The synthesis and structure Of (CH3CH[NH3]CH2NH3)(1/2) . ZnPO4, an organically templated zincophosphate (ZnPO) analogue of aluminosilicate zeolite thomsonite (THO), are described. The ZnPO framework is built up from an alternating, vertex-sharing, network of ZnO4 and PO4 groups (d(av)(Zn-O) = 1.944 (8) Angstrom, d(av)(P-O) = 1.535 (9) Angstrom, theta(av)(Zn-O-P) = 130.5degrees) involving distinctive 4 = I secondary building units. The 1,2-diammonium propane cations are highly disordered in the [0 0 1] 8-ring channels. Crystal data: (CH3CH[NH3]CH2NH3)(1-2) . ZnPO4, M-r = 198.42, orthorhombic, space group Pnen (no. 52), a = 14.119 (6) Angstrom, b = 14.136 (5) Angstrom, c = 12.985 (5) Angstrom, V = 2591 (3) Angstrom(3), Z = 10, R(F) = 0.057, R-w(F) = 0.061 (for a twinned crystal). (C) 2001 Elsevier Science B.V. All rights reserved.

AB - The synthesis and structure Of (CH3CH[NH3]CH2NH3)(1/2) . ZnPO4, an organically templated zincophosphate (ZnPO) analogue of aluminosilicate zeolite thomsonite (THO), are described. The ZnPO framework is built up from an alternating, vertex-sharing, network of ZnO4 and PO4 groups (d(av)(Zn-O) = 1.944 (8) Angstrom, d(av)(P-O) = 1.535 (9) Angstrom, theta(av)(Zn-O-P) = 130.5degrees) involving distinctive 4 = I secondary building units. The 1,2-diammonium propane cations are highly disordered in the [0 0 1] 8-ring channels. Crystal data: (CH3CH[NH3]CH2NH3)(1-2) . ZnPO4, M-r = 198.42, orthorhombic, space group Pnen (no. 52), a = 14.119 (6) Angstrom, b = 14.136 (5) Angstrom, c = 12.985 (5) Angstrom, V = 2591 (3) Angstrom(3), Z = 10, R(F) = 0.057, R-w(F) = 0.061 (for a twinned crystal). (C) 2001 Elsevier Science B.V. All rights reserved.

KW - fibrous zeolite

KW - crystal structure

KW - twinning

KW - zinc

KW - PHOSPHATES

KW - TOPOLOGY

U2 - 10.1016/S1387-1811(01)00451-6

DO - 10.1016/S1387-1811(01)00451-6

M3 - Article

VL - 50

SP - 187

EP - 194

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

SN - 1387-1811

ER -