(CN3H6)(2)center dot Zn4H5(PO4)(5), a new layered guanidinium zinc phosphate built up from 3-, 4-, and 8-ring units

W T A Harrison, M L F Phillips, W Clegg, S J Teat

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

The solution-mediated synthesis and single crystal structure of (CN3H6)(2) . Zn4H5(PO4)(5), a new guanidinium zinc phosphate, are described. The use of high-intensity synchrotron radiation was necessary to determine the correct unit cell for this phase, Unlike the previously described one-dimensional or three-dimensional guanidinium zinc phosphates, this material has a strongly layered nature. Vertex-linked ZnO4, HPO4, and H2PO4 building units self-assemble into complex sheets containing polyhedral 3-rings, 4-rings, and 8-rings. The intersheet guanidinium cations provide charge compensation and interact with the layers via N-H ... O hydrogen bonds, Crystal data: (CN3H6)(2) . Zn4H5 (PO4)(5), M-r = 861.57, monoclinic, space group I2/a (No, 15), a = 23.770 (2) Angstrom, b = 5.1036 (5) Angstrom, c = 18.100 (2) Angstrom, beta = 94.491 (2)degrees, V = 2189.0 (5) Angstrom(3), Z = 4, R(F) = 0.047, R-w(F-2) = 0.121 (2322 reflections, 168 parameters). (C) 1999 Academic Press.

Original languageEnglish
Pages (from-to)433-437
Number of pages5
JournalJournal of Solid State Chemistry
Volume148
Publication statusPublished - 1999

Keywords

  • TETRAHEDRAL 3-RINGS
  • CRYSTALLOGRAPHY

Cite this

(CN3H6)(2)center dot Zn4H5(PO4)(5), a new layered guanidinium zinc phosphate built up from 3-, 4-, and 8-ring units. / Harrison, W T A ; Phillips, M L F ; Clegg, W ; Teat, S J .

In: Journal of Solid State Chemistry, Vol. 148, 1999, p. 433-437.

Research output: Contribution to journalArticle

@article{432b1e5babca4ad9bdf1358badc237fe,
title = "(CN3H6)(2)center dot Zn4H5(PO4)(5), a new layered guanidinium zinc phosphate built up from 3-, 4-, and 8-ring units",
abstract = "The solution-mediated synthesis and single crystal structure of (CN3H6)(2) . Zn4H5(PO4)(5), a new guanidinium zinc phosphate, are described. The use of high-intensity synchrotron radiation was necessary to determine the correct unit cell for this phase, Unlike the previously described one-dimensional or three-dimensional guanidinium zinc phosphates, this material has a strongly layered nature. Vertex-linked ZnO4, HPO4, and H2PO4 building units self-assemble into complex sheets containing polyhedral 3-rings, 4-rings, and 8-rings. The intersheet guanidinium cations provide charge compensation and interact with the layers via N-H ... O hydrogen bonds, Crystal data: (CN3H6)(2) . Zn4H5 (PO4)(5), M-r = 861.57, monoclinic, space group I2/a (No, 15), a = 23.770 (2) Angstrom, b = 5.1036 (5) Angstrom, c = 18.100 (2) Angstrom, beta = 94.491 (2)degrees, V = 2189.0 (5) Angstrom(3), Z = 4, R(F) = 0.047, R-w(F-2) = 0.121 (2322 reflections, 168 parameters). (C) 1999 Academic Press.",
keywords = "TETRAHEDRAL 3-RINGS, CRYSTALLOGRAPHY",
author = "Harrison, {W T A} and Phillips, {M L F} and W Clegg and Teat, {S J}",
year = "1999",
language = "English",
volume = "148",
pages = "433--437",
journal = "Journal of Solid State Chemistry",
issn = "0022-4596",
publisher = "ACADEMIC PRESS INC ELSEVIER SCIENCE",

}

TY - JOUR

T1 - (CN3H6)(2)center dot Zn4H5(PO4)(5), a new layered guanidinium zinc phosphate built up from 3-, 4-, and 8-ring units

AU - Harrison, W T A

AU - Phillips, M L F

AU - Clegg, W

AU - Teat, S J

PY - 1999

Y1 - 1999

N2 - The solution-mediated synthesis and single crystal structure of (CN3H6)(2) . Zn4H5(PO4)(5), a new guanidinium zinc phosphate, are described. The use of high-intensity synchrotron radiation was necessary to determine the correct unit cell for this phase, Unlike the previously described one-dimensional or three-dimensional guanidinium zinc phosphates, this material has a strongly layered nature. Vertex-linked ZnO4, HPO4, and H2PO4 building units self-assemble into complex sheets containing polyhedral 3-rings, 4-rings, and 8-rings. The intersheet guanidinium cations provide charge compensation and interact with the layers via N-H ... O hydrogen bonds, Crystal data: (CN3H6)(2) . Zn4H5 (PO4)(5), M-r = 861.57, monoclinic, space group I2/a (No, 15), a = 23.770 (2) Angstrom, b = 5.1036 (5) Angstrom, c = 18.100 (2) Angstrom, beta = 94.491 (2)degrees, V = 2189.0 (5) Angstrom(3), Z = 4, R(F) = 0.047, R-w(F-2) = 0.121 (2322 reflections, 168 parameters). (C) 1999 Academic Press.

AB - The solution-mediated synthesis and single crystal structure of (CN3H6)(2) . Zn4H5(PO4)(5), a new guanidinium zinc phosphate, are described. The use of high-intensity synchrotron radiation was necessary to determine the correct unit cell for this phase, Unlike the previously described one-dimensional or three-dimensional guanidinium zinc phosphates, this material has a strongly layered nature. Vertex-linked ZnO4, HPO4, and H2PO4 building units self-assemble into complex sheets containing polyhedral 3-rings, 4-rings, and 8-rings. The intersheet guanidinium cations provide charge compensation and interact with the layers via N-H ... O hydrogen bonds, Crystal data: (CN3H6)(2) . Zn4H5 (PO4)(5), M-r = 861.57, monoclinic, space group I2/a (No, 15), a = 23.770 (2) Angstrom, b = 5.1036 (5) Angstrom, c = 18.100 (2) Angstrom, beta = 94.491 (2)degrees, V = 2189.0 (5) Angstrom(3), Z = 4, R(F) = 0.047, R-w(F-2) = 0.121 (2322 reflections, 168 parameters). (C) 1999 Academic Press.

KW - TETRAHEDRAL 3-RINGS

KW - CRYSTALLOGRAPHY

M3 - Article

VL - 148

SP - 433

EP - 437

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

SN - 0022-4596

ER -