Abstract
The solution-mediated synthesis and single crystal structure of (CN3H6)(2). Zn(HPO3)(2) are reported. This phase is built up from a three-dimensional framework of vertex-linked ZnO4 and HPO3 building units encapsulating the extraframework guanidinium cations. The structure is stabilised by template-to-framework hydrogen bonding. The inorganic framework contains polyhedral 12-rings and shows a surprising similarity to those of some known organically-templated zinc phosphates.
Original language | English |
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Pages (from-to) | 2459-2461 |
Number of pages | 3 |
Journal | Journal of the Chemical Society, Dalton Transactions |
Publication status | Published - 2001 |
Keywords
- PHOSPHATE
- HYDROGEN
- NETS