(CN3H6)(2)center dot Zn(HPO3)(2): An open-framework zincophosphite built up from polyhedral 12-rings

W T A  Harrison; M L F  Phillips; T M  Nenoff

(CN3H6)(2)center dot Zn(HPO3)(2): An open-framework zincophosphite built up from polyhedral 12-rings

W T A Harrison, M L F Phillips, T M Nenoff

Chemistry

Research output: Contribution to journal › Article

Abstract

The solution-mediated synthesis and single crystal structure of (CN3H6)(2). Zn(HPO3)(2) are reported. This phase is built up from a three-dimensional framework of vertex-linked ZnO4 and HPO3 building units encapsulating the extraframework guanidinium cations. The structure is stabilised by template-to-framework hydrogen bonding. The inorganic framework contains polyhedral 12-rings and shows a surprising similarity to those of some known organically-templated zinc phosphates.

Original language	English
Pages (from-to)	2459-2461
Number of pages	3
Journal	Journal of the Chemical Society, Dalton Transactions
Publication status	Published - 2001

Keywords

PHOSPHATE
HYDROGEN
NETS

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title = "(CN3H6)(2)center dot Zn(HPO3)(2): An open-framework zincophosphite built up from polyhedral 12-rings",

abstract = "The solution-mediated synthesis and single crystal structure of (CN3H6)(2). Zn(HPO3)(2) are reported. This phase is built up from a three-dimensional framework of vertex-linked ZnO4 and HPO3 building units encapsulating the extraframework guanidinium cations. The structure is stabilised by template-to-framework hydrogen bonding. The inorganic framework contains polyhedral 12-rings and shows a surprising similarity to those of some known organically-templated zinc phosphates.",

keywords = "PHOSPHATE, HYDROGEN, NETS",

author = "Harrison, {W T A} and Phillips, {M L F} and Nenoff, {T M}",

year = "2001",

language = "English",

pages = "2459--2461",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "1472-7773",

publisher = "ROYAL SOC CHEMISTRY",

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T1 - (CN3H6)(2)center dot Zn(HPO3)(2): An open-framework zincophosphite built up from polyhedral 12-rings

AU - Harrison, W T A

AU - Phillips, M L F

AU - Nenoff, T M

PY - 2001

Y1 - 2001

N2 - The solution-mediated synthesis and single crystal structure of (CN3H6)(2). Zn(HPO3)(2) are reported. This phase is built up from a three-dimensional framework of vertex-linked ZnO4 and HPO3 building units encapsulating the extraframework guanidinium cations. The structure is stabilised by template-to-framework hydrogen bonding. The inorganic framework contains polyhedral 12-rings and shows a surprising similarity to those of some known organically-templated zinc phosphates.

AB - The solution-mediated synthesis and single crystal structure of (CN3H6)(2). Zn(HPO3)(2) are reported. This phase is built up from a three-dimensional framework of vertex-linked ZnO4 and HPO3 building units encapsulating the extraframework guanidinium cations. The structure is stabilised by template-to-framework hydrogen bonding. The inorganic framework contains polyhedral 12-rings and shows a surprising similarity to those of some known organically-templated zinc phosphates.

KW - PHOSPHATE

KW - HYDROGEN

KW - NETS

M3 - Article

SN - 1472-7773

SP - 2459

EP - 2461

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

ER -

(CN3H6)(2)center dot Zn(HPO3)(2): An open-framework zincophosphite built up from polyhedral 12-rings

Abstract

Keywords

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