(CN3H6)2·(VO)3(H2O)3(HPO3)4·3H2O, a guanidinium vanadium phosphite hydrate based on a (3,4) connected net: an “Orthogonal Templating” effect?

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Abstract

(CN3H6)(2)(.)(VO)(3)(H2O)(3)(HPO3)(4)(.)3H(2)O, a new guanidnium-templated vanadium(IV) phosphite is built up from a (3,4) net of VO5(H2O) pseudo squares and HPO3 pseudo pyramids, sharing vertices as V-O-P bonds. These polyhedra self assemble around the extra-framework guanidinium cations and water molecules, which appear to exert their templating effects in orthogonal directions, to result in a very-low-density framework containing intersecting 12-ring channels. Crystal data: (CN3H6)(2)(.)(VO)(3)(H2O)(3)(HPO3)(4)(.)3H(2)O, M-r = 749.00, orthorhombic, Pna2(1) (No. 33), a = 19.0766(13) Angstrom,b = 9.1657(6) Angstrom, c = 14.1806(9) Angstrom, V = 2479.5(3) Angstrom(3), Z = 4, R = 0.050, R-w = 0.094. (C) 2002 Editions scientifiques et medicales Elsevier SAS. All rights reserved.

Original languageEnglish
Pages (from-to)297-302
Number of pages6
JournalSolid State Sciences
Volume5
Issue number2
Early online date6 Nov 2002
DOIs
Publication statusPublished - Feb 2003

Fingerprint

Phosphites
Vanadium
Guanidine
pyramids
polyhedrons
Hydrates
hydrates
vanadium
Cations
apexes
Positive ions
cations
Crystals
Molecules
Water
rings
water
crystals
molecules
Direction compound

Keywords

  • framework zincophosphite
  • hydrothermal synthesis
  • crystal-structure
  • bond valences
  • built-up
  • hydrogen
  • solids

Cite this

@article{d55dbdf613814ef9af1d4988160e577b,
title = "(CN3H6)2·(VO)3(H2O)3(HPO3)4·3H2O, a guanidinium vanadium phosphite hydrate based on a (3,4) connected net: an “Orthogonal Templating” effect?",
abstract = "(CN3H6)(2)(.)(VO)(3)(H2O)(3)(HPO3)(4)(.)3H(2)O, a new guanidnium-templated vanadium(IV) phosphite is built up from a (3,4) net of VO5(H2O) pseudo squares and HPO3 pseudo pyramids, sharing vertices as V-O-P bonds. These polyhedra self assemble around the extra-framework guanidinium cations and water molecules, which appear to exert their templating effects in orthogonal directions, to result in a very-low-density framework containing intersecting 12-ring channels. Crystal data: (CN3H6)(2)(.)(VO)(3)(H2O)(3)(HPO3)(4)(.)3H(2)O, M-r = 749.00, orthorhombic, Pna2(1) (No. 33), a = 19.0766(13) Angstrom,b = 9.1657(6) Angstrom, c = 14.1806(9) Angstrom, V = 2479.5(3) Angstrom(3), Z = 4, R = 0.050, R-w = 0.094. (C) 2002 Editions scientifiques et medicales Elsevier SAS. All rights reserved.",
keywords = "framework zincophosphite, hydrothermal synthesis, crystal-structure, bond valences, built-up, hydrogen, solids",
author = "Harrison, {W T A}",
year = "2003",
month = "2",
doi = "10.1016/S1293-2558(02)00020-1",
language = "English",
volume = "5",
pages = "297--302",
journal = "Solid State Sciences",
issn = "1293-2558",
publisher = "Elsevier Masson SAS",
number = "2",

}

TY - JOUR

T1 - (CN3H6)2·(VO)3(H2O)3(HPO3)4·3H2O, a guanidinium vanadium phosphite hydrate based on a (3,4) connected net: an “Orthogonal Templating” effect?

AU - Harrison, W T A

PY - 2003/2

Y1 - 2003/2

N2 - (CN3H6)(2)(.)(VO)(3)(H2O)(3)(HPO3)(4)(.)3H(2)O, a new guanidnium-templated vanadium(IV) phosphite is built up from a (3,4) net of VO5(H2O) pseudo squares and HPO3 pseudo pyramids, sharing vertices as V-O-P bonds. These polyhedra self assemble around the extra-framework guanidinium cations and water molecules, which appear to exert their templating effects in orthogonal directions, to result in a very-low-density framework containing intersecting 12-ring channels. Crystal data: (CN3H6)(2)(.)(VO)(3)(H2O)(3)(HPO3)(4)(.)3H(2)O, M-r = 749.00, orthorhombic, Pna2(1) (No. 33), a = 19.0766(13) Angstrom,b = 9.1657(6) Angstrom, c = 14.1806(9) Angstrom, V = 2479.5(3) Angstrom(3), Z = 4, R = 0.050, R-w = 0.094. (C) 2002 Editions scientifiques et medicales Elsevier SAS. All rights reserved.

AB - (CN3H6)(2)(.)(VO)(3)(H2O)(3)(HPO3)(4)(.)3H(2)O, a new guanidnium-templated vanadium(IV) phosphite is built up from a (3,4) net of VO5(H2O) pseudo squares and HPO3 pseudo pyramids, sharing vertices as V-O-P bonds. These polyhedra self assemble around the extra-framework guanidinium cations and water molecules, which appear to exert their templating effects in orthogonal directions, to result in a very-low-density framework containing intersecting 12-ring channels. Crystal data: (CN3H6)(2)(.)(VO)(3)(H2O)(3)(HPO3)(4)(.)3H(2)O, M-r = 749.00, orthorhombic, Pna2(1) (No. 33), a = 19.0766(13) Angstrom,b = 9.1657(6) Angstrom, c = 14.1806(9) Angstrom, V = 2479.5(3) Angstrom(3), Z = 4, R = 0.050, R-w = 0.094. (C) 2002 Editions scientifiques et medicales Elsevier SAS. All rights reserved.

KW - framework zincophosphite

KW - hydrothermal synthesis

KW - crystal-structure

KW - bond valences

KW - built-up

KW - hydrogen

KW - solids

U2 - 10.1016/S1293-2558(02)00020-1

DO - 10.1016/S1293-2558(02)00020-1

M3 - Article

VL - 5

SP - 297

EP - 302

JO - Solid State Sciences

JF - Solid State Sciences

SN - 1293-2558

IS - 2

ER -