Crystal structure of 1, 7, 8, 9-tetrachloro-4-(2-fluorobenzyl)-10, 10-dimethoxy-4-azatricyclo[5.2.1.02, 6]dec-8-ene-3, 5-dione

Jia Liang Zhong; Jia Wei Hou; Li Hong Liu; He Liu; W. T A Harrison

doi:10.1107/S2056989014026279

Crystal structure of 1, 7, 8, 9-tetrachloro-4-(2-fluorobenzyl)-10, 10-dimethoxy-4-azatricyclo[5.2.1.0^{2, 6}]dec-8-ene-3, 5-dione

Jia Liang Zhong, Jia Wei Hou, Li Hong Liu^*, He Liu, W. T A Harrison (Editor)

^*Corresponding author for this work

Chemistry

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Abstract

In the title compound, C₁₇H₁₂Cl₄FNO₄, the configuration of the cycloalkene skeleton is endo, cis. The benzene ring is twisted by 71.01 (11)° from the attached pyrrolidine ring. In the crystal, one of the methine groups of the fused-ring system forms a weak C - H⋯O hydrogen bond. The other methine groups participates in a C - H⋯F interaction to the same adjacent molecule. Together, these generate [010] chains.

Original language	English
Pages (from-to)	o32
Number of pages	1
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	71
Issue number	1
Early online date	1 Jan 2015
DOIs	https://doi.org/10.1107/S2056989014026279
Publication status	Published - 1 Jan 2015

Keywords

Biochemical activity
C - H⋯F interaction
Crystal structure
Hydrogen bonding
Tricyclo[5,2,1,02,6]dec-8-ene-3,5-dione

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10.1107/S2056989014026279Licence: CC BY

Crystal structure of 1, 7, 8, 9-tetrachloro-4-(2-fluorobenzyl)-10, 10-dimethoxy-4-azatricyclo[5.2.1.02, 6]dec-8-ene-3, 5-dione
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Final published version, 388 KBLicence: CC BY

Cite this

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title = "Crystal structure of 1, 7, 8, 9-tetrachloro-4-(2-fluorobenzyl)-10, 10-dimethoxy-4-azatricyclo[5.2.1.02, 6]dec-8-ene-3, 5-dione",

abstract = "In the title compound, C17H12Cl4FNO4, the configuration of the cycloalkene skeleton is endo, cis. The benzene ring is twisted by 71.01 (11)° from the attached pyrrolidine ring. In the crystal, one of the methine groups of the fused-ring system forms a weak C - H⋯O hydrogen bond. The other methine groups participates in a C - H⋯F interaction to the same adjacent molecule. Together, these generate [010] chains.",

keywords = "Biochemical activity, C - H⋯F interaction, Crystal structure, Hydrogen bonding, Tricyclo[5,2,1,02,6]dec-8-ene-3,5-dione",

author = "Zhong, {Jia Liang} and Hou, {Jia Wei} and Liu, {Li Hong} and He Liu and Harrison, {W. T A}",

note = "Acknowledgements We gratefully acknowledge financial support from the National Natural Science Foundation of China (No.81072530).",

year = "2015",

month = jan,

day = "1",

doi = "10.1107/S2056989014026279",

language = "English",

volume = "71",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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publisher = "International Union of Crystallography",

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TY - JOUR

T1 - Crystal structure of 1, 7, 8, 9-tetrachloro-4-(2-fluorobenzyl)-10, 10-dimethoxy-4-azatricyclo[5.2.1.02, 6]dec-8-ene-3, 5-dione

AU - Zhong, Jia Liang

AU - Hou, Jia Wei

AU - Liu, Li Hong

AU - Liu, He

A2 - Harrison, W. T A

N1 - Acknowledgements We gratefully acknowledge financial support from the National Natural Science Foundation of China (No.81072530).

PY - 2015/1/1

Y1 - 2015/1/1

N2 - In the title compound, C17H12Cl4FNO4, the configuration of the cycloalkene skeleton is endo, cis. The benzene ring is twisted by 71.01 (11)° from the attached pyrrolidine ring. In the crystal, one of the methine groups of the fused-ring system forms a weak C - H⋯O hydrogen bond. The other methine groups participates in a C - H⋯F interaction to the same adjacent molecule. Together, these generate [010] chains.

AB - In the title compound, C17H12Cl4FNO4, the configuration of the cycloalkene skeleton is endo, cis. The benzene ring is twisted by 71.01 (11)° from the attached pyrrolidine ring. In the crystal, one of the methine groups of the fused-ring system forms a weak C - H⋯O hydrogen bond. The other methine groups participates in a C - H⋯F interaction to the same adjacent molecule. Together, these generate [010] chains.

KW - Biochemical activity

KW - C - H⋯F interaction

KW - Crystal structure

KW - Hydrogen bonding

KW - Tricyclo[5,2,1,02,6]dec-8-ene-3,5-dione

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U2 - 10.1107/S2056989014026279

DO - 10.1107/S2056989014026279

M3 - Article

VL - 71

SP - o32

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 1

ER -

Crystal structure of 1, 7, 8, 9-tetrachloro-4-(2-fluorobenzyl)-10, 10-dimethoxy-4-azatricyclo[5.2.1.0^{2, 6}]dec-8-ene-3, 5-dione

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