Crystal structure of 1-butyl-2,3-di-methylimidazolium dicarba-7,8-nido-undecaborate

M. J. Klemes; L. Soderstrom; J. L. Hunting; A. S. Larsen; W. T A Harrison

doi:10.1107/S2056989015002765

Crystal structure of 1-butyl-2,3-di-methylimidazolium dicarba-7,8-nido-undecaborate

M. J. Klemes, L. Soderstrom, J. L. Hunting, A. S. Larsen^*, W. T A Harrison (Editor)

^*Corresponding author for this work

Chemistry

Ithaca College

Research output: Contribution to journal › Article › peer-review

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Abstract

In the title molecular salt, C₉H₁₇N2⁺·C₂H₁₂B₉^-, the carborane cage has a bridging B - H - B bond on the open B₃C₂ face. The butyl side chain of the cation adopts an extended conformation [C - C - C - C = 179.6 (1)°]. In the crystal, the imidazo-lium ring is almost coplanar with the open face of the carborane anion. The cations stack in the [010] direction and the dihedral angle between the imidazolium rings of adjacent cations is 68.45 (6)°. The butyl chains extend into the space between carborane anions.

Original language	English
Pages (from-to)	o183
Number of pages	1
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	71
Issue number	3
Early online date	13 Feb 2015
DOIs	https://doi.org/10.1107/S2056989015002765
Publication status	Published - 1 Mar 2015

Bibliographical note

AL thanks Professor Maitland Jones for the generous donation of the starting orthocarborane stock and Dr John Holbrey for the supply of imidazolium halide reagents. The research
support by ACS PRF and Cottrell College awards (44692.01-GB and CC6755) is gratefully acknowledged.

Keywords

Bridging B - H - B bond
Carborane cage anion
Crystal structure
Imidazolium cation

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10.1107/S2056989015002765Licence: CC BY

Crystal structure of 1-butyl-2,3-di-methylimidazolium dicarba-7,8-nidoundecaborate
© 2015 Klemeset al. Licence: Creative Commons Attribution (CC-BY) https://creativecommons.org/licenses/by/4.0/
Final published version, 585 KBLicence: CC BY

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title = "Crystal structure of 1-butyl-2,3-di-methylimidazolium dicarba-7,8-nido-undecaborate",

abstract = "In the title molecular salt, C9H17N2+·C2H12B9-, the carborane cage has a bridging B - H - B bond on the open B3C2 face. The butyl side chain of the cation adopts an extended conformation [C - C - C - C = 179.6 (1)°]. In the crystal, the imidazo-lium ring is almost coplanar with the open face of the carborane anion. The cations stack in the [010] direction and the dihedral angle between the imidazolium rings of adjacent cations is 68.45 (6)°. The butyl chains extend into the space between carborane anions.",

keywords = "Bridging B - H - B bond, Carborane cage anion, Crystal structure, Imidazolium cation",

author = "Klemes, {M. J.} and L. Soderstrom and Hunting, {J. L.} and Larsen, {A. S.} and Harrison, {W. T A}",

note = "AL thanks Professor Maitland Jones for the generous donation of the starting orthocarborane stock and Dr John Holbrey for the supply of imidazolium halide reagents. The research support by ACS PRF and Cottrell College awards (44692.01-GB and CC6755) is gratefully acknowledged.",

year = "2015",

month = mar,

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doi = "10.1107/S2056989015002765",

language = "English",

volume = "71",

pages = "o183",

journal = "Acta Crystallographica Section E: Structure Reports Online",

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publisher = "International Union of Crystallography",

number = "3",

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TY - JOUR

T1 - Crystal structure of 1-butyl-2,3-di-methylimidazolium dicarba-7,8-nido-undecaborate

AU - Klemes, M. J.

AU - Soderstrom, L.

AU - Hunting, J. L.

AU - Larsen, A. S.

A2 - Harrison, W. T A

N1 - AL thanks Professor Maitland Jones for the generous donation of the starting orthocarborane stock and Dr John Holbrey for the supply of imidazolium halide reagents. The research support by ACS PRF and Cottrell College awards (44692.01-GB and CC6755) is gratefully acknowledged.

PY - 2015/3/1

Y1 - 2015/3/1

N2 - In the title molecular salt, C9H17N2+·C2H12B9-, the carborane cage has a bridging B - H - B bond on the open B3C2 face. The butyl side chain of the cation adopts an extended conformation [C - C - C - C = 179.6 (1)°]. In the crystal, the imidazo-lium ring is almost coplanar with the open face of the carborane anion. The cations stack in the [010] direction and the dihedral angle between the imidazolium rings of adjacent cations is 68.45 (6)°. The butyl chains extend into the space between carborane anions.

AB - In the title molecular salt, C9H17N2+·C2H12B9-, the carborane cage has a bridging B - H - B bond on the open B3C2 face. The butyl side chain of the cation adopts an extended conformation [C - C - C - C = 179.6 (1)°]. In the crystal, the imidazo-lium ring is almost coplanar with the open face of the carborane anion. The cations stack in the [010] direction and the dihedral angle between the imidazolium rings of adjacent cations is 68.45 (6)°. The butyl chains extend into the space between carborane anions.

KW - Bridging B - H - B bond

KW - Carborane cage anion

KW - Crystal structure

KW - Imidazolium cation

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DO - 10.1107/S2056989015002765

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AN - SCOPUS:84928161651

SN - 1600-5368

VL - 71

SP - o183

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 3

ER -

Crystal structure of 1-butyl-2,3-di-methylimidazolium dicarba-7,8-nido-undecaborate

Abstract

Bibliographical note

Keywords

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