Crystal structure of 2-{(E)-[(2-hydroxy-phenyl) iminiumyl]methyl}-4-methyl-phenolate

Suresh Shalini; C. R. Girija; Mukesh M. Jotani; C. D. Sathish; T. V. Venkatesha; W. T A Harrison

doi:10.1107/S2056989015006374

Crystal structure of 2-{(E)-[(2-hydroxy-phenyl) iminiumyl]methyl}-4-methyl-phenolate

Suresh Shalini, C. R. Girija^*, Mukesh M. Jotani, C. D. Sathish, T. V. Venkatesha, W. T A Harrison (Editor)

^*Corresponding author for this work

Chemistry

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Abstract

The title compound, C₁₄H₁₃NO₂, exists as a zwitterion in the solid state, with the H atom of the phenol group transferred to the imine N atom. The dihedral angle between the planes of the benzene rings is 10.13 (9)°. Intramolecular N - H⋯O hydrogen bond generate S(6) and S(5) loops. In the crystal, molecules are connected by O - H⋯O hydrogen bonds, generating C(9) chains propagating in the [010] direction.

Original language	English
Pages (from-to)	o288
Number of pages	1
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	71
Issue number	5
Early online date	9 Apr 2015
DOIs	https://doi.org/10.1107/S2056989015006374
Publication status	Published - 1 May 2015

Keywords

Crystal structure
Hydrogen bonding
N-(salicylidene)aniline
Schiff base
Zwitterion

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10.1107/S2056989015006374Licence: CC BY

Crystal structure of 2-{(E)-[(2-hydroxyphenyl)iminiumyl]methyl}-4-methylphenolate
© 2015 Shaliniet al. Licence: Creative Commons Attribution (CC-BY) https://creativecommons.org/licenses/by/4.0/
Final published version, 331 KBLicence: CC BY

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title = "Crystal structure of 2-{(E)-[(2-hydroxy-phenyl) iminiumyl]methyl}-4-methyl-phenolate",

abstract = "The title compound, C14H13NO2, exists as a zwitterion in the solid state, with the H atom of the phenol group transferred to the imine N atom. The dihedral angle between the planes of the benzene rings is 10.13 (9)°. Intramolecular N - H⋯O hydrogen bond generate S(6) and S(5) loops. In the crystal, molecules are connected by O - H⋯O hydrogen bonds, generating C(9) chains propagating in the [010] direction.",

keywords = "Crystal structure, Hydrogen bonding, N-(salicylidene)aniline, Schiff base, Zwitterion",

author = "Suresh Shalini and Girija, {C. R.} and Jotani, {Mukesh M.} and Sathish, {C. D.} and Venkatesha, {T. V.} and Harrison, {W. T A}",

note = "The authors thank SSCU, IISc, Bangalore, India, for the X-ray intensity data collection. SS and CRG thank RSST and the Principal, SSMRV Degree College, Bangalore, for their constant support and encouragement for carrying out research work.",

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doi = "10.1107/S2056989015006374",

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T1 - Crystal structure of 2-{(E)-[(2-hydroxy-phenyl) iminiumyl]methyl}-4-methyl-phenolate

AU - Shalini, Suresh

AU - Girija, C. R.

AU - Jotani, Mukesh M.

AU - Sathish, C. D.

AU - Venkatesha, T. V.

A2 - Harrison, W. T A

N1 - The authors thank SSCU, IISc, Bangalore, India, for the X-ray intensity data collection. SS and CRG thank RSST and the Principal, SSMRV Degree College, Bangalore, for their constant support and encouragement for carrying out research work.

PY - 2015/5/1

Y1 - 2015/5/1

N2 - The title compound, C14H13NO2, exists as a zwitterion in the solid state, with the H atom of the phenol group transferred to the imine N atom. The dihedral angle between the planes of the benzene rings is 10.13 (9)°. Intramolecular N - H⋯O hydrogen bond generate S(6) and S(5) loops. In the crystal, molecules are connected by O - H⋯O hydrogen bonds, generating C(9) chains propagating in the [010] direction.

AB - The title compound, C14H13NO2, exists as a zwitterion in the solid state, with the H atom of the phenol group transferred to the imine N atom. The dihedral angle between the planes of the benzene rings is 10.13 (9)°. Intramolecular N - H⋯O hydrogen bond generate S(6) and S(5) loops. In the crystal, molecules are connected by O - H⋯O hydrogen bonds, generating C(9) chains propagating in the [010] direction.

KW - Crystal structure

KW - Hydrogen bonding

KW - N-(salicylidene)aniline

KW - Schiff base

KW - Zwitterion

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JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

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Crystal structure of 2-{(E)-[(2-hydroxy-phenyl) iminiumyl]methyl}-4-methyl-phenolate

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Keywords

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