Crystal structure of 2-{(E)-[(2-hydroxy-phenyl) iminiumyl]methyl}-4-methyl-phenolate

Suresh Shalini, C. R. Girija*, Mukesh M. Jotani, C. D. Sathish, T. V. Venkatesha, W. T A Harrison (Editor)

*Corresponding author for this work

Research output: Contribution to journalArticle

2 Citations (Scopus)
4 Downloads (Pure)

Abstract

The title compound, C14H13NO2, exists as a zwitterion in the solid state, with the H atom of the phenol group transferred to the imine N atom. The dihedral angle between the planes of the benzene rings is 10.13 (9)°. Intramolecular N - H⋯O hydrogen bond generate S(6) and S(5) loops. In the crystal, molecules are connected by O - H⋯O hydrogen bonds, generating C(9) chains propagating in the [010] direction.

Original languageEnglish
Pages (from-to)o288
Number of pages1
JournalActa Crystallographica Section E: Structure Reports Online
Volume71
Issue number5
Early online date9 Apr 2015
DOIs
Publication statusPublished - 1 May 2015

Fingerprint

Hydrogen bonds
Crystal structure
hydrogen bonds
Atoms
crystal structure
zwitterions
Imines
Dihedral angle
Phenol
Benzene
phenols
imines
Phenols
atoms
dihedral angle
benzene
solid state
Crystals
Molecules
rings

Keywords

  • Crystal structure
  • Hydrogen bonding
  • N-(salicylidene)aniline
  • Schiff base
  • Zwitterion

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

Crystal structure of 2-{(E)-[(2-hydroxy-phenyl) iminiumyl]methyl}-4-methyl-phenolate. / Shalini, Suresh; Girija, C. R.; Jotani, Mukesh M.; Sathish, C. D.; Venkatesha, T. V.; Harrison, W. T A (Editor).

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 71, No. 5, 01.05.2015, p. o288.

Research output: Contribution to journalArticle

Shalini, Suresh ; Girija, C. R. ; Jotani, Mukesh M. ; Sathish, C. D. ; Venkatesha, T. V. ; Harrison, W. T A (Editor). / Crystal structure of 2-{(E)-[(2-hydroxy-phenyl) iminiumyl]methyl}-4-methyl-phenolate. In: Acta Crystallographica Section E: Structure Reports Online. 2015 ; Vol. 71, No. 5. pp. o288.
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abstract = "The title compound, C14H13NO2, exists as a zwitterion in the solid state, with the H atom of the phenol group transferred to the imine N atom. The dihedral angle between the planes of the benzene rings is 10.13 (9)°. Intramolecular N - H⋯O hydrogen bond generate S(6) and S(5) loops. In the crystal, molecules are connected by O - H⋯O hydrogen bonds, generating C(9) chains propagating in the [010] direction.",
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AU - Venkatesha, T. V.

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