Crystal structure of 2-{(E)-[(2-hydroxy-phenyl) iminiumyl]methyl}-4-methyl-phenolate

Suresh Shalini; C. R. Girija; Mukesh M. Jotani; C. D. Sathish; T. V. Venkatesha; W. T A Harrison

doi:10.1107/S2056989015006374

Crystal structure of 2-{(E)-[(2-hydroxy-phenyl) iminiumyl]methyl}-4-methyl-phenolate

Suresh Shalini, C. R. Girija^*, Mukesh M. Jotani, C. D. Sathish, T. V. Venkatesha, W. T A Harrison (Editor)

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

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Abstract

The title compound, C₁₄H₁₃NO₂, exists as a zwitterion in the solid state, with the H atom of the phenol group transferred to the imine N atom. The dihedral angle between the planes of the benzene rings is 10.13 (9)°. Intramolecular N - H⋯O hydrogen bond generate S(6) and S(5) loops. In the crystal, molecules are connected by O - H⋯O hydrogen bonds, generating C(9) chains propagating in the [010] direction.

Original language	English
Pages (from-to)	o288
Number of pages	1
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	71
Issue number	5
Early online date	9 Apr 2015
DOIs	https://doi.org/10.1107/S2056989015006374
Publication status	Published - 1 May 2015

Bibliographical note

The authors thank SSCU, IISc, Bangalore, India, for the X-ray intensity data collection. SS and CRG thank RSST and the Principal, SSMRV Degree College, Bangalore, for their constant support and encouragement for carrying out research work.

Keywords

Crystal structure
Hydrogen bonding
N-(salicylidene)aniline
Schiff base
Zwitterion

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10.1107/S2056989015006374Licence: CC BY

Crystal structure of 2-{(E)-[(2-hydroxyphenyl)iminiumyl]methyl}-4-methylphenolate
© 2015 Shaliniet al. Licence: Creative Commons Attribution (CC-BY) https://creativecommons.org/licenses/by/4.0/
Final published version, 331 KBLicence: CC BY

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title = "Crystal structure of 2-{(E)-[(2-hydroxy-phenyl) iminiumyl]methyl}-4-methyl-phenolate",

abstract = "The title compound, C14H13NO2, exists as a zwitterion in the solid state, with the H atom of the phenol group transferred to the imine N atom. The dihedral angle between the planes of the benzene rings is 10.13 (9)°. Intramolecular N - H⋯O hydrogen bond generate S(6) and S(5) loops. In the crystal, molecules are connected by O - H⋯O hydrogen bonds, generating C(9) chains propagating in the [010] direction.",

keywords = "Crystal structure, Hydrogen bonding, N-(salicylidene)aniline, Schiff base, Zwitterion",

author = "Suresh Shalini and Girija, {C. R.} and Jotani, {Mukesh M.} and Sathish, {C. D.} and Venkatesha, {T. V.} and Harrison, {W. T A}",

note = "The authors thank SSCU, IISc, Bangalore, India, for the X-ray intensity data collection. SS and CRG thank RSST and the Principal, SSMRV Degree College, Bangalore, for their constant support and encouragement for carrying out research work.",

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T1 - Crystal structure of 2-{(E)-[(2-hydroxy-phenyl) iminiumyl]methyl}-4-methyl-phenolate

AU - Shalini, Suresh

AU - Girija, C. R.

AU - Jotani, Mukesh M.

AU - Sathish, C. D.

AU - Venkatesha, T. V.

A2 - Harrison, W. T A

N1 - The authors thank SSCU, IISc, Bangalore, India, for the X-ray intensity data collection. SS and CRG thank RSST and the Principal, SSMRV Degree College, Bangalore, for their constant support and encouragement for carrying out research work.

PY - 2015/5/1

Y1 - 2015/5/1

N2 - The title compound, C14H13NO2, exists as a zwitterion in the solid state, with the H atom of the phenol group transferred to the imine N atom. The dihedral angle between the planes of the benzene rings is 10.13 (9)°. Intramolecular N - H⋯O hydrogen bond generate S(6) and S(5) loops. In the crystal, molecules are connected by O - H⋯O hydrogen bonds, generating C(9) chains propagating in the [010] direction.

AB - The title compound, C14H13NO2, exists as a zwitterion in the solid state, with the H atom of the phenol group transferred to the imine N atom. The dihedral angle between the planes of the benzene rings is 10.13 (9)°. Intramolecular N - H⋯O hydrogen bond generate S(6) and S(5) loops. In the crystal, molecules are connected by O - H⋯O hydrogen bonds, generating C(9) chains propagating in the [010] direction.

KW - Crystal structure

KW - Hydrogen bonding

KW - N-(salicylidene)aniline

KW - Schiff base

KW - Zwitterion

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Crystal structure of 2-{(E)-[(2-hydroxy-phenyl) iminiumyl]methyl}-4-methyl-phenolate

Abstract

Bibliographical note

Keywords

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