Crystal structure of 3,3′-diisopropyl-1,1′-(pyridine-2,6-diyl) bis[1H-imidazole-2(3H)-thione]

Ying Sun*, Hui Wang, Wei Guo Jia, William Thomas Alexander Harrison

*Corresponding author for this work

Research output: Contribution to journalArticle

Abstract

In the title compound, C17H21N5S2, the dihedral angles between the central pyridine ring and its pendant imidazole rings are 29.40 (9) and 40.77 (9)°; the pendant rings are twisted in an opposite sense with respect to the central ring. In each case, the S atom is approximately anti to the N atom of the pyridine ring. For both substituents, the H atom attached to the central C atom of the isopropyl group is approximately syn to the S atom in the attached ring. In the crystal, molecules are linked by weak C - H⋯S interactions, generating C(5) chains propagating along [001].

Original languageEnglish
Pages (from-to)o255
Number of pages6
JournalActa Crystallographica Section E: Structure Reports Online
Volume71
Issue number4
DOIs
Publication statusPublished - 1 Apr 2015

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Thiones
imidazoles
Pyridine
pyridines
Crystal structure
Atoms
crystal structure
rings
atoms
Dihedral angle
dihedral angle
pyridine
imidazole
Crystals
Molecules
crystals
molecules

Keywords

  • C - H⋯S interactions
  • Conformation
  • Crystal structure
  • Organochalcogen ligand

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

Crystal structure of 3,3′-diisopropyl-1,1′-(pyridine-2,6-diyl) bis[1H-imidazole-2(3H)-thione]. / Sun, Ying; Wang, Hui; Jia, Wei Guo; Harrison, William Thomas Alexander.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 71, No. 4, 01.04.2015, p. o255.

Research output: Contribution to journalArticle

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AU - Jia, Wei Guo

AU - Harrison, William Thomas Alexander

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