TY - JOUR
T1 - Crystal structure of 3,3′-diisopropyl-1,1′-(pyridine-2,6-diyl) bis[1H-imidazole-2(3H)-thione]
AU - Sun, Ying
AU - Wang, Hui
AU - Jia, Wei Guo
AU - Harrison, William Thomas Alexander
PY - 2015/4/1
Y1 - 2015/4/1
N2 - In the title compound, C17H21N5S2, the dihedral angles between the central pyridine ring and its pendant imidazole rings are 29.40 (9) and 40.77 (9)°; the pendant rings are twisted in an opposite sense with respect to the central ring. In each case, the S atom is approximately anti to the N atom of the pyridine ring. For both substituents, the H atom attached to the central C atom of the isopropyl group is approximately syn to the S atom in the attached ring. In the crystal, molecules are linked by weak C - H⋯S interactions, generating C(5) chains propagating along [001].
AB - In the title compound, C17H21N5S2, the dihedral angles between the central pyridine ring and its pendant imidazole rings are 29.40 (9) and 40.77 (9)°; the pendant rings are twisted in an opposite sense with respect to the central ring. In each case, the S atom is approximately anti to the N atom of the pyridine ring. For both substituents, the H atom attached to the central C atom of the isopropyl group is approximately syn to the S atom in the attached ring. In the crystal, molecules are linked by weak C - H⋯S interactions, generating C(5) chains propagating along [001].
KW - C - H⋯S interactions
KW - Conformation
KW - Crystal structure
KW - Organochalcogen ligand
UR - http://www.scopus.com/inward/record.url?scp=84928114269&partnerID=8YFLogxK
U2 - 10.1107/S2056989015005642
DO - 10.1107/S2056989015005642
M3 - Article
AN - SCOPUS:84928114269
SN - 1600-5368
VL - 71
SP - o255
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 4
ER -