Crystal structure of (E)-N-[(2-chloro-6-methoxy-quinolin-3-yl) methylidene]-9-ethyl-9H-carbazol-3-amine

Kannan Thirumurthy; Ganesamoorthy Thirunarayanan; S. Murugavel; William Thomas Alexander Harrison

doi:10.1107/S2056989015005794

Crystal structure of (E)-N-[(2-chloro-6-methoxy-quinolin-3-yl) methylidene]-9-ethyl-9H-carbazol-3-amine

Kannan Thirumurthy, Ganesamoorthy Thirunarayanan^*, S. Murugavel, William Thomas Alexander Harrison

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

In the title compound, C₂₅H₂₀ClN₃O, the C=N bond of the central imine group adopts an E conformation. The mean planes through the essentially planar carbazole [maximum deviation = 0.052 (2)Å] and quinoline [maximum deviation = 0.050 (2) Å] ring systems form a dihedral angle of 50.2 (1)°. In the crystal, molecules are linked by C - H⋯π and π - π interactions [centroid-centroid distances ranging from 3.635 (2) to 3.739 (2) Å], forming a three-dimensional supramolecular network.

Original language	English
Pages (from-to)	421-423
Number of pages	3
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	71
Issue number	4
DOIs	https://doi.org/10.1107/S2056989015005794
Publication status	Published - 1 Apr 2015

Bibliographical note

Acknowledgements
The authors thank Professor M. Periasamy, School of Chemistry, University of Hyderabad, for providing laboratory facilities and are also grateful to the UGC Networking Resource Centre, School of Chemistry, University of Hyderabad, for providing characterization facilities.

Keywords

9-ethyl-9H-carbazol-3-amine
C - H⋯πinteractions
Carbazole
Crystal packing
Crystal structure
Quinoline
π-πinteractions

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title = "Crystal structure of (E)-N-[(2-chloro-6-methoxy-quinolin-3-yl) methylidene]-9-ethyl-9H-carbazol-3-amine",

abstract = "In the title compound, C25H20ClN3O, the C=N bond of the central imine group adopts an E conformation. The mean planes through the essentially planar carbazole [maximum deviation = 0.052 (2){\AA}] and quinoline [maximum deviation = 0.050 (2) {\AA}] ring systems form a dihedral angle of 50.2 (1)°. In the crystal, molecules are linked by C - H⋯π and π - π interactions [centroid-centroid distances ranging from 3.635 (2) to 3.739 (2) {\AA}], forming a three-dimensional supramolecular network.",

keywords = "9-ethyl-9H-carbazol-3-amine, C - H⋯πinteractions, Carbazole, Crystal packing, Crystal structure, Quinoline, π-πinteractions",

author = "Kannan Thirumurthy and Ganesamoorthy Thirunarayanan and S. Murugavel and Harrison, {William Thomas Alexander}",

note = "Acknowledgements The authors thank Professor M. Periasamy, School of Chemistry, University of Hyderabad, for providing laboratory facilities and are also grateful to the UGC Networking Resource Centre, School of Chemistry, University of Hyderabad, for providing characterization facilities.",

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doi = "10.1107/S2056989015005794",

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volume = "71",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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T1 - Crystal structure of (E)-N-[(2-chloro-6-methoxy-quinolin-3-yl) methylidene]-9-ethyl-9H-carbazol-3-amine

AU - Thirumurthy, Kannan

AU - Thirunarayanan, Ganesamoorthy

AU - Murugavel, S.

AU - Harrison, William Thomas Alexander

N1 - Acknowledgements The authors thank Professor M. Periasamy, School of Chemistry, University of Hyderabad, for providing laboratory facilities and are also grateful to the UGC Networking Resource Centre, School of Chemistry, University of Hyderabad, for providing characterization facilities.

PY - 2015/4/1

Y1 - 2015/4/1

N2 - In the title compound, C25H20ClN3O, the C=N bond of the central imine group adopts an E conformation. The mean planes through the essentially planar carbazole [maximum deviation = 0.052 (2)Å] and quinoline [maximum deviation = 0.050 (2) Å] ring systems form a dihedral angle of 50.2 (1)°. In the crystal, molecules are linked by C - H⋯π and π - π interactions [centroid-centroid distances ranging from 3.635 (2) to 3.739 (2) Å], forming a three-dimensional supramolecular network.

AB - In the title compound, C25H20ClN3O, the C=N bond of the central imine group adopts an E conformation. The mean planes through the essentially planar carbazole [maximum deviation = 0.052 (2)Å] and quinoline [maximum deviation = 0.050 (2) Å] ring systems form a dihedral angle of 50.2 (1)°. In the crystal, molecules are linked by C - H⋯π and π - π interactions [centroid-centroid distances ranging from 3.635 (2) to 3.739 (2) Å], forming a three-dimensional supramolecular network.

KW - 9-ethyl-9H-carbazol-3-amine

KW - C - H⋯πinteractions

KW - Carbazole

KW - Crystal packing

KW - Crystal structure

KW - Quinoline

KW - π-πinteractions

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DO - 10.1107/S2056989015005794

M3 - Article

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SN - 1600-5368

VL - 71

SP - 421

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JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 4

ER -

Crystal structure of (E)-N-[(2-chloro-6-methoxy-quinolin-3-yl) methylidene]-9-ethyl-9H-carbazol-3-amine

Abstract

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Keywords

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