Crystal structure of (E)-N-[(2-chloro-6-methoxy-quinolin-3-yl) methylidene]-9-ethyl-9H-carbazol-3-amine

Kannan Thirumurthy, Ganesamoorthy Thirunarayanan*, S. Murugavel, William Thomas Alexander Harrison

*Corresponding author for this work

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

In the title compound, C25H20ClN3O, the C=N bond of the central imine group adopts an E conformation. The mean planes through the essentially planar carbazole [maximum deviation = 0.052 (2)Å] and quinoline [maximum deviation = 0.050 (2) Å] ring systems form a dihedral angle of 50.2 (1)°. In the crystal, molecules are linked by C - H⋯π and π - π interactions [centroid-centroid distances ranging from 3.635 (2) to 3.739 (2) Å], forming a three-dimensional supramolecular network.

Original languageEnglish
Pages (from-to)421-423
Number of pages3
JournalActa Crystallographica Section E: Structure Reports Online
Volume71
Issue number4
DOIs
Publication statusPublished - 1 Apr 2015

Fingerprint

Imines
quinoline
Dihedral angle
centroids
Conformations
Amines
amines
Crystal structure
deviation
Crystals
crystal structure
Molecules
carbazoles
imines
dihedral angle
rings
crystals
molecules
interactions
3-amino-9-ethylcarbazole

Keywords

  • 9-ethyl-9H-carbazol-3-amine
  • C - H⋯πinteractions
  • Carbazole
  • Crystal packing
  • Crystal structure
  • Quinoline
  • π-πinteractions

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

Crystal structure of (E)-N-[(2-chloro-6-methoxy-quinolin-3-yl) methylidene]-9-ethyl-9H-carbazol-3-amine. / Thirumurthy, Kannan; Thirunarayanan, Ganesamoorthy; Murugavel, S.; Harrison, William Thomas Alexander.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 71, No. 4, 01.04.2015, p. 421-423.

Research output: Contribution to journalArticle

@article{407d23f276804518bb6e83a07952e181,
title = "Crystal structure of (E)-N-[(2-chloro-6-methoxy-quinolin-3-yl) methylidene]-9-ethyl-9H-carbazol-3-amine",
abstract = "In the title compound, C25H20ClN3O, the C=N bond of the central imine group adopts an E conformation. The mean planes through the essentially planar carbazole [maximum deviation = 0.052 (2){\AA}] and quinoline [maximum deviation = 0.050 (2) {\AA}] ring systems form a dihedral angle of 50.2 (1)°. In the crystal, molecules are linked by C - H⋯π and π - π interactions [centroid-centroid distances ranging from 3.635 (2) to 3.739 (2) {\AA}], forming a three-dimensional supramolecular network.",
keywords = "9-ethyl-9H-carbazol-3-amine, C - H⋯πinteractions, Carbazole, Crystal packing, Crystal structure, Quinoline, π-πinteractions",
author = "Kannan Thirumurthy and Ganesamoorthy Thirunarayanan and S. Murugavel and Harrison, {William Thomas Alexander}",
note = "Acknowledgements The authors thank Professor M. Periasamy, School of Chemistry, University of Hyderabad, for providing laboratory facilities and are also grateful to the UGC Networking Resource Centre, School of Chemistry, University of Hyderabad, for providing characterization facilities.",
year = "2015",
month = "4",
day = "1",
doi = "10.1107/S2056989015005794",
language = "English",
volume = "71",
pages = "421--423",
journal = "Acta Crystallographica Section E: Structure Reports Online",
issn = "1600-5368",
publisher = "International Union of Crystallography",
number = "4",

}

TY - JOUR

T1 - Crystal structure of (E)-N-[(2-chloro-6-methoxy-quinolin-3-yl) methylidene]-9-ethyl-9H-carbazol-3-amine

AU - Thirumurthy, Kannan

AU - Thirunarayanan, Ganesamoorthy

AU - Murugavel, S.

AU - Harrison, William Thomas Alexander

N1 - Acknowledgements The authors thank Professor M. Periasamy, School of Chemistry, University of Hyderabad, for providing laboratory facilities and are also grateful to the UGC Networking Resource Centre, School of Chemistry, University of Hyderabad, for providing characterization facilities.

PY - 2015/4/1

Y1 - 2015/4/1

N2 - In the title compound, C25H20ClN3O, the C=N bond of the central imine group adopts an E conformation. The mean planes through the essentially planar carbazole [maximum deviation = 0.052 (2)Å] and quinoline [maximum deviation = 0.050 (2) Å] ring systems form a dihedral angle of 50.2 (1)°. In the crystal, molecules are linked by C - H⋯π and π - π interactions [centroid-centroid distances ranging from 3.635 (2) to 3.739 (2) Å], forming a three-dimensional supramolecular network.

AB - In the title compound, C25H20ClN3O, the C=N bond of the central imine group adopts an E conformation. The mean planes through the essentially planar carbazole [maximum deviation = 0.052 (2)Å] and quinoline [maximum deviation = 0.050 (2) Å] ring systems form a dihedral angle of 50.2 (1)°. In the crystal, molecules are linked by C - H⋯π and π - π interactions [centroid-centroid distances ranging from 3.635 (2) to 3.739 (2) Å], forming a three-dimensional supramolecular network.

KW - 9-ethyl-9H-carbazol-3-amine

KW - C - H⋯πinteractions

KW - Carbazole

KW - Crystal packing

KW - Crystal structure

KW - Quinoline

KW - π-πinteractions

UR - http://www.scopus.com/inward/record.url?scp=84928106973&partnerID=8YFLogxK

U2 - 10.1107/S2056989015005794

DO - 10.1107/S2056989015005794

M3 - Article

VL - 71

SP - 421

EP - 423

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

SN - 1600-5368

IS - 4

ER -