Abstract
Two heterometallic decavanadate(V) compounds, bis(tetramethylammonium) decaaquadi-μ4-oxido-tetra-μ3-oxido-hexadeca-μ2-oxido-hexaoxidodimangan-ese(II)decavanadate(V) pentahydrate, (Me4N)2[V10O28{Mn(H2O)5}2]·5H2O, A, and bis{[tris(hydroxymethyl)methyl]ammonium} decaaquadi-μ4-oxido-tetra-μ3-oxido-hexadeca-μ2-oxido-hexaoxidodimanganese(II)decavanadate(V) dihydrate, [NH3C(CH2OH)3]2[V10O28{Mn(H2O)5}2]·2H2O, B, have been synthesized under mild reaction conditions in an aqueous medium. Both polyanions present two [Mn(OH2)5]2+ complex units bound to the decavanadate cluster through oxide bridges. In A, the decavanadate unit has 2/m symmetry, whereas in B it has twofold symmetry. Apart from this, the main differences between A and B rest on the organic cations, tetramethylammonium and [tris(hydroxy-methyl) methyl]ammonium, respectively, and on the number and arrangement of the water molecules of crystallization. In both compounds, the H atoms from the coordinating water molecules participate in extensive three-dimensional hydrogen-bonding networks, which link the cluster units both directly and through solvent molecules and, in B, through the 'tris' cation hydroxyl groups. The cation in B also participates in N - H⋯O hydrogen bonds. A number of C - H⋯O interactions are also observed in both structures.
| Original language | English |
|---|---|
| Pages (from-to) | 146-150 |
| Number of pages | 5 |
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Volume | 71 |
| Issue number | 2 |
| Early online date | 10 Jan 2015 |
| DOIs | |
| Publication status | Published - 1 Feb 2015 |
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Keywords
- Crystal structure
- Decavanadate
- Heteropolyanion
- Manganese(II)
- Organic cations
ASJC Scopus subject areas
- Condensed Matter Physics
- Materials Science(all)
- Chemistry(all)
Cite this
Crystal structures of two decavanadates(V) with pentaaquamanganese(II) pendant groups : (NMe4)2[V10O28{Mn(H2O)5}2]·5H2O and [NH3C(CH2OH)3]2[V10O28{Mn(H2O)5}2]·2H2O. / Franco, Maurício P.; Rüdiger, André Luis; Soares, Jaísa F.; Nunes, Giovana G.; Hughes, David L.; Harrison, W. T A (Editor).
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 71, No. 2, 01.02.2015, p. 146-150.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Crystal structures of two decavanadates(V) with pentaaquamanganese(II) pendant groups
T2 - (NMe4)2[V10O28{Mn(H2O)5}2]·5H2O and [NH3C(CH2OH)3]2[V10O28{Mn(H2O)5}2]·2H2O
AU - Franco, Maurício P.
AU - Rüdiger, André Luis
AU - Soares, Jaísa F.
AU - Nunes, Giovana G.
AU - Hughes, David L.
A2 - Harrison, W. T A
N1 - Financial support from the Brazilian agencies CNPq (grant No. 307592/2012–0) and CAPES (grant PVE A099/2013) is gratefully acknowledged. The authors also thank CNPq, CAPES and Fundação Araucária (Brazil) for fellowships.
PY - 2015/2/1
Y1 - 2015/2/1
N2 - Two heterometallic decavanadate(V) compounds, bis(tetramethylammonium) decaaquadi-μ4-oxido-tetra-μ3-oxido-hexadeca-μ2-oxido-hexaoxidodimangan-ese(II)decavanadate(V) pentahydrate, (Me4N)2[V10O28{Mn(H2O)5}2]·5H2O, A, and bis{[tris(hydroxymethyl)methyl]ammonium} decaaquadi-μ4-oxido-tetra-μ3-oxido-hexadeca-μ2-oxido-hexaoxidodimanganese(II)decavanadate(V) dihydrate, [NH3C(CH2OH)3]2[V10O28{Mn(H2O)5}2]·2H2O, B, have been synthesized under mild reaction conditions in an aqueous medium. Both polyanions present two [Mn(OH2)5]2+ complex units bound to the decavanadate cluster through oxide bridges. In A, the decavanadate unit has 2/m symmetry, whereas in B it has twofold symmetry. Apart from this, the main differences between A and B rest on the organic cations, tetramethylammonium and [tris(hydroxy-methyl) methyl]ammonium, respectively, and on the number and arrangement of the water molecules of crystallization. In both compounds, the H atoms from the coordinating water molecules participate in extensive three-dimensional hydrogen-bonding networks, which link the cluster units both directly and through solvent molecules and, in B, through the 'tris' cation hydroxyl groups. The cation in B also participates in N - H⋯O hydrogen bonds. A number of C - H⋯O interactions are also observed in both structures.
AB - Two heterometallic decavanadate(V) compounds, bis(tetramethylammonium) decaaquadi-μ4-oxido-tetra-μ3-oxido-hexadeca-μ2-oxido-hexaoxidodimangan-ese(II)decavanadate(V) pentahydrate, (Me4N)2[V10O28{Mn(H2O)5}2]·5H2O, A, and bis{[tris(hydroxymethyl)methyl]ammonium} decaaquadi-μ4-oxido-tetra-μ3-oxido-hexadeca-μ2-oxido-hexaoxidodimanganese(II)decavanadate(V) dihydrate, [NH3C(CH2OH)3]2[V10O28{Mn(H2O)5}2]·2H2O, B, have been synthesized under mild reaction conditions in an aqueous medium. Both polyanions present two [Mn(OH2)5]2+ complex units bound to the decavanadate cluster through oxide bridges. In A, the decavanadate unit has 2/m symmetry, whereas in B it has twofold symmetry. Apart from this, the main differences between A and B rest on the organic cations, tetramethylammonium and [tris(hydroxy-methyl) methyl]ammonium, respectively, and on the number and arrangement of the water molecules of crystallization. In both compounds, the H atoms from the coordinating water molecules participate in extensive three-dimensional hydrogen-bonding networks, which link the cluster units both directly and through solvent molecules and, in B, through the 'tris' cation hydroxyl groups. The cation in B also participates in N - H⋯O hydrogen bonds. A number of C - H⋯O interactions are also observed in both structures.
KW - Crystal structure
KW - Decavanadate
KW - Heteropolyanion
KW - Manganese(II)
KW - Organic cations
UR - http://www.scopus.com/inward/record.url?scp=84928107400&partnerID=8YFLogxK
U2 - 10.1107/S2056989014028230
DO - 10.1107/S2056989014028230
M3 - Article
VL - 71
SP - 146
EP - 150
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
SN - 1600-5368
IS - 2
ER -