Crystallisation of H3BTC, H3TPO or H2SDA with MII (M = Co, Mn or Zn) and 2,2′-bipyridyl: Design and control of co-ordination architecture, and magnetic properties (H3BTC = benzene-1,3,5-tricarboxylic acid, H3TPO = tris(4-carboxylphenyl)phosphine oxide, H2SDA = cis-stilbene-4,4′-dicarboxylic acid)

M. John Plater; Mark R.St J. Foreman; Eugenio Coronado; Carlos J. Gómez-Garcí; Alexandra M.Z. Slawin

doi:10.1039/a905332h

Crystallisation of H₃BTC, H₃TPO or H₂SDA with M^II (M = Co, Mn or Zn) and 2,2′-bipyridyl: Design and control of co-ordination architecture, and magnetic properties (H₃BTC = benzene-1,3,5-tricarboxylic acid, H₃TPO = tris(4-carboxylphenyl)phosphine oxide, H₂SDA = cis-stilbene-4,4′-dicarboxylic acid)

M. John Plater^*, Mark R.St J. Foreman, Eugenio Coronado, Carlos J. Gómez-Garcí, Alexandra M.Z. Slawin

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

134 Citations (Scopus)

Abstract

The hydrothermal reaction of benzene-1,3,5-tricarboxylic acid (H₃BTC) with M^II (M = Mn, Co or Zn), tris(4-carboxyphenyl)phosphine oxide (H₃TPO) or cis-stilbene-4,4′-dicarboxylic acid (H₂SDA) with Co^II and 2,2′-bipyridyl (BIPY) gave 1-D co-ordination networks formulated as: [M(HBTC)(BIPY)(H₂O)] (M = Mn 1, Co 2, or Zn 3; [Co₃(BTC)₂-(BIPY)₂(H₂O) ₆]·4H₂O 4, [Co₃(TPO)₂(BIPY)₂(H₂O) ₆]·xH₂O 5 and [Co(SDA)(BIPY)(H₂O)] 6. Structures 1 and 2 consist of double stranded chains of alternating HBTC dianions and dimeric units M^II-M^II linked by two μ-(1,1) bridging carboxylates. Magnetic properties of 1 and 2 indicate the presence of ferromagnetic exchange interactions within the dimers. Structures 4 and 5 consist of chains with a molecular ladder motif which are stacked creating large channels lined by hydrated cobalt(II) ions. The H₂O/D₂O solvent exchange in structure 5, studied by infrared spectroscopy and thermal gravimetric analysis-mass spectrometry, provides evidence for the porosity and zeolitic nature of the material.

Original language	English
Pages (from-to)	4209-4216
Number of pages	8
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	23
DOIs	https://doi.org/10.1039/a905332h
Publication status	Published - 7 Dec 1999

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We are grateful to the Leverhulme Trust for financial support.

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Plater, M. J., Foreman, M. R. S. J., Coronado, E., Gómez-Garcí, C. J., & Slawin, A. M. Z. (1999). Crystallisation of H₃BTC, H₃TPO or H₂SDA with M^II (M = Co, Mn or Zn) and 2,2′-bipyridyl: Design and control of co-ordination architecture, and magnetic properties (H₃BTC = benzene-1,3,5-tricarboxylic acid, H₃TPO = tris(4-carboxylphenyl)phosphine oxide, H₂SDA = cis-stilbene-4,4′-dicarboxylic acid). Journal of the Chemical Society, Dalton Transactions, (23), 4209-4216. https://doi.org/10.1039/a905332h

Crystallisation of H₃BTC, H₃TPO or H₂SDA with M^II (M = Co, Mn or Zn) and 2,2′-bipyridyl: Design and control of co-ordination architecture, and magnetic properties (H₃BTC = benzene-1,3,5-tricarboxylic acid, H₃TPO = tris(4-carboxylphenyl)phosphine oxide, H₂SDA = cis-stilbene-4,4′-dicarboxylic acid). / Plater, M. John; Foreman, Mark R.St J.; Coronado, Eugenio et al.
In: Journal of the Chemical Society, Dalton Transactions, No. 23, 07.12.1999, p. 4209-4216.

Research output: Contribution to journal › Article › peer-review

Plater, MJ, Foreman, MRSJ, Coronado, E, Gómez-Garcí, CJ & Slawin, AMZ 1999, 'Crystallisation of H₃BTC, H₃TPO or H₂SDA with M^II (M = Co, Mn or Zn) and 2,2′-bipyridyl: Design and control of co-ordination architecture, and magnetic properties (H₃BTC = benzene-1,3,5-tricarboxylic acid, H₃TPO = tris(4-carboxylphenyl)phosphine oxide, H₂SDA = cis-stilbene-4,4′-dicarboxylic acid)', Journal of the Chemical Society, Dalton Transactions, no. 23, pp. 4209-4216. https://doi.org/10.1039/a905332h

Plater MJ, Foreman MRSJ, Coronado E, Gómez-Garcí CJ, Slawin AMZ. Crystallisation of H₃BTC, H₃TPO or H₂SDA with M^II (M = Co, Mn or Zn) and 2,2′-bipyridyl: Design and control of co-ordination architecture, and magnetic properties (H₃BTC = benzene-1,3,5-tricarboxylic acid, H₃TPO = tris(4-carboxylphenyl)phosphine oxide, H₂SDA = cis-stilbene-4,4′-dicarboxylic acid). Journal of the Chemical Society, Dalton Transactions. 1999 Dec 7;(23):4209-4216. doi: 10.1039/a905332h

Plater, M. John ; Foreman, Mark R.St J. ; Coronado, Eugenio et al. / Crystallisation of H₃BTC, H₃TPO or H₂SDA with M^II (M = Co, Mn or Zn) and 2,2′-bipyridyl : Design and control of co-ordination architecture, and magnetic properties (H₃BTC = benzene-1,3,5-tricarboxylic acid, H₃TPO = tris(4-carboxylphenyl)phosphine oxide, H₂SDA = cis-stilbene-4,4′-dicarboxylic acid). In: Journal of the Chemical Society, Dalton Transactions. 1999 ; No. 23. pp. 4209-4216.

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title = "Crystallisation of H3BTC, H3TPO or H2SDA with MII (M = Co, Mn or Zn) and 2,2′-bipyridyl: Design and control of co-ordination architecture, and magnetic properties (H3BTC = benzene-1,3,5-tricarboxylic acid, H3TPO = tris(4-carboxylphenyl)phosphine oxide, H2SDA = cis-stilbene-4,4′-dicarboxylic acid)",

abstract = "The hydrothermal reaction of benzene-1,3,5-tricarboxylic acid (H3BTC) with MII (M = Mn, Co or Zn), tris(4-carboxyphenyl)phosphine oxide (H3TPO) or cis-stilbene-4,4′-dicarboxylic acid (H2SDA) with CoII and 2,2′-bipyridyl (BIPY) gave 1-D co-ordination networks formulated as: [M(HBTC)(BIPY)(H2O)] (M = Mn 1, Co 2, or Zn 3; [Co3(BTC)2-(BIPY)2(H2O) 6]·4H2O 4, [Co3(TPO)2(BIPY)2(H2O) 6]·xH2O 5 and [Co(SDA)(BIPY)(H2O)] 6. Structures 1 and 2 consist of double stranded chains of alternating HBTC dianions and dimeric units MII-MII linked by two μ-(1,1) bridging carboxylates. Magnetic properties of 1 and 2 indicate the presence of ferromagnetic exchange interactions within the dimers. Structures 4 and 5 consist of chains with a molecular ladder motif which are stacked creating large channels lined by hydrated cobalt(II) ions. The H2O/D2O solvent exchange in structure 5, studied by infrared spectroscopy and thermal gravimetric analysis-mass spectrometry, provides evidence for the porosity and zeolitic nature of the material.",

author = "Plater, {M. John} and Foreman, {Mark R.St J.} and Eugenio Coronado and G{\'o}mez-Garc{\'i}, {Carlos J.} and Slawin, {Alexandra M.Z.}",

note = "We are grateful to the Leverhulme Trust for financial support.",

year = "1999",

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T1 - Crystallisation of H3BTC, H3TPO or H2SDA with MII (M = Co, Mn or Zn) and 2,2′-bipyridyl

T2 - Design and control of co-ordination architecture, and magnetic properties (H3BTC = benzene-1,3,5-tricarboxylic acid, H3TPO = tris(4-carboxylphenyl)phosphine oxide, H2SDA = cis-stilbene-4,4′-dicarboxylic acid)

AU - Plater, M. John

AU - Foreman, Mark R.St J.

AU - Coronado, Eugenio

AU - Gómez-Garcí, Carlos J.

AU - Slawin, Alexandra M.Z.

N1 - We are grateful to the Leverhulme Trust for financial support.

PY - 1999/12/7

Y1 - 1999/12/7

N2 - The hydrothermal reaction of benzene-1,3,5-tricarboxylic acid (H3BTC) with MII (M = Mn, Co or Zn), tris(4-carboxyphenyl)phosphine oxide (H3TPO) or cis-stilbene-4,4′-dicarboxylic acid (H2SDA) with CoII and 2,2′-bipyridyl (BIPY) gave 1-D co-ordination networks formulated as: [M(HBTC)(BIPY)(H2O)] (M = Mn 1, Co 2, or Zn 3; [Co3(BTC)2-(BIPY)2(H2O) 6]·4H2O 4, [Co3(TPO)2(BIPY)2(H2O) 6]·xH2O 5 and [Co(SDA)(BIPY)(H2O)] 6. Structures 1 and 2 consist of double stranded chains of alternating HBTC dianions and dimeric units MII-MII linked by two μ-(1,1) bridging carboxylates. Magnetic properties of 1 and 2 indicate the presence of ferromagnetic exchange interactions within the dimers. Structures 4 and 5 consist of chains with a molecular ladder motif which are stacked creating large channels lined by hydrated cobalt(II) ions. The H2O/D2O solvent exchange in structure 5, studied by infrared spectroscopy and thermal gravimetric analysis-mass spectrometry, provides evidence for the porosity and zeolitic nature of the material.

AB - The hydrothermal reaction of benzene-1,3,5-tricarboxylic acid (H3BTC) with MII (M = Mn, Co or Zn), tris(4-carboxyphenyl)phosphine oxide (H3TPO) or cis-stilbene-4,4′-dicarboxylic acid (H2SDA) with CoII and 2,2′-bipyridyl (BIPY) gave 1-D co-ordination networks formulated as: [M(HBTC)(BIPY)(H2O)] (M = Mn 1, Co 2, or Zn 3; [Co3(BTC)2-(BIPY)2(H2O) 6]·4H2O 4, [Co3(TPO)2(BIPY)2(H2O) 6]·xH2O 5 and [Co(SDA)(BIPY)(H2O)] 6. Structures 1 and 2 consist of double stranded chains of alternating HBTC dianions and dimeric units MII-MII linked by two μ-(1,1) bridging carboxylates. Magnetic properties of 1 and 2 indicate the presence of ferromagnetic exchange interactions within the dimers. Structures 4 and 5 consist of chains with a molecular ladder motif which are stacked creating large channels lined by hydrated cobalt(II) ions. The H2O/D2O solvent exchange in structure 5, studied by infrared spectroscopy and thermal gravimetric analysis-mass spectrometry, provides evidence for the porosity and zeolitic nature of the material.

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JO - Journal of the Chemical Society, Dalton Transactions

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