Dicarbonyl-bis(1,10-phenanthroline)molybdenum(0)

Kathleen J. Muir, Geoffrey P. McQuillan, William T. A. Harrison

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

In the title compound, [Mo(CO)2(phen)2] (phen = C12H8N2), the Mo atom adopts a cis-MoC2N4 geometry. The C-Mo-C angle of 88.0 (3)° is close to its ideal, undistorted value and the dihedral angle between the phen mean planes is 84.79 (9)°. A C-HO bond and various pi-pi stacking interactions [centroid-centroid separation = 3.472 (3)-3.890 (4) Å] may help to establish the packing.
Original languageEnglish
Article numberm2491
Number of pages11
JournalActa Crystallographica Section E: Structure Reports Online
Volume63
Issue number10
DOIs
Publication statusPublished - Oct 2007

Keywords

  • crystal

Cite this

Dicarbonyl-bis(1,10-phenanthroline)molybdenum(0). / Muir, Kathleen J.; McQuillan, Geoffrey P.; Harrison, William T. A.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 63, No. 10, m2491, 10.2007.

Research output: Contribution to journalArticle

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AB - In the title compound, [Mo(CO)2(phen)2] (phen = C12H8N2), the Mo atom adopts a cis-MoC2N4 geometry. The C-Mo-C angle of 88.0 (3)° is close to its ideal, undistorted value and the dihedral angle between the phen mean planes is 84.79 (9)°. A C-HO bond and various pi-pi stacking interactions [centroid-centroid separation = 3.472 (3)-3.890 (4) Å] may help to establish the packing.

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