Dicarbonyl-bis(1,10-phenanthroline)molybdenum(0)

Kathleen J. Muir; Geoffrey P. McQuillan; William T. A. Harrison

doi:10.1107/S1600536807042791

Dicarbonyl-bis(1,10-phenanthroline)molybdenum(0)

Kathleen J. Muir, Geoffrey P. McQuillan, William T. A. Harrison

Chemistry

Research output: Contribution to journal › Article

4 Citations (Scopus)

Abstract

In the title compound, [Mo(CO)2(phen)2] (phen = C12H8N2), the Mo atom adopts a cis-MoC2N4 geometry. The C-Mo-C angle of 88.0 (3)° is close to its ideal, undistorted value and the dihedral angle between the phen mean planes is 84.79 (9)°. A C-HO bond and various pi-pi stacking interactions [centroid-centroid separation = 3.472 (3)-3.890 (4) Å] may help to establish the packing.

Original language	English
Article number	m2491
Number of pages	11
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	63
Issue number	10
DOIs	https://doi.org/10.1107/S1600536807042791
Publication status	Published - Oct 2007

Keywords

crystal

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10.1107/S1600536807042791

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title = "Dicarbonyl-bis(1,10-phenanthroline)molybdenum(0)",

abstract = "In the title compound, [Mo(CO)2(phen)2] (phen = C12H8N2), the Mo atom adopts a cis-MoC2N4 geometry. The C-Mo-C angle of 88.0 (3)° is close to its ideal, undistorted value and the dihedral angle between the phen mean planes is 84.79 (9)°. A C-HO bond and various pi-pi stacking interactions [centroid-centroid separation = 3.472 (3)-3.890 (4) {\AA}] may help to establish the packing.",

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author = "Muir, {Kathleen J.} and McQuillan, {Geoffrey P.} and Harrison, {William T. A.}",

year = "2007",

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doi = "10.1107/S1600536807042791",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

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T1 - Dicarbonyl-bis(1,10-phenanthroline)molybdenum(0)

AU - Muir, Kathleen J.

AU - McQuillan, Geoffrey P.

AU - Harrison, William T. A.

PY - 2007/10

Y1 - 2007/10

N2 - In the title compound, [Mo(CO)2(phen)2] (phen = C12H8N2), the Mo atom adopts a cis-MoC2N4 geometry. The C-Mo-C angle of 88.0 (3)° is close to its ideal, undistorted value and the dihedral angle between the phen mean planes is 84.79 (9)°. A C-HO bond and various pi-pi stacking interactions [centroid-centroid separation = 3.472 (3)-3.890 (4) Å] may help to establish the packing.

AB - In the title compound, [Mo(CO)2(phen)2] (phen = C12H8N2), the Mo atom adopts a cis-MoC2N4 geometry. The C-Mo-C angle of 88.0 (3)° is close to its ideal, undistorted value and the dihedral angle between the phen mean planes is 84.79 (9)°. A C-HO bond and various pi-pi stacking interactions [centroid-centroid separation = 3.472 (3)-3.890 (4) Å] may help to establish the packing.

KW - crystal

U2 - 10.1107/S1600536807042791

DO - 10.1107/S1600536807042791

M3 - Article

SN - 1600-5368

VL - 63

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 10

M1 - m2491

ER -

Dicarbonyl-bis(1,10-phenanthroline)molybdenum(0)

Abstract

Keywords

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