Hydrogen bonding in C-substituted nitroanilines: sheets built from alternating R-2(2)(12) and R-6(6)(36) rings in 2-bromo-6-cyano-4-nitroaniline

C Glidewell, J N Low, S A McWilliam, Jan Skakle, J L Wardell

Research output: Contribution to journal › Article

7 Citations (Scopus)

Abstract

Molecules of the title compound (systematic name: 2-amino-3-bromo-5-nitrobenzonitrile), C7H4BrN3O2, are linked by N-H...N and N-H...O hydrogen bonds [H...N 2.19 Angstrom, N...N 3.019 (4) Angstrom and N-H...N 157degrees, and H...O 2.17 Angstrom, N...O 2.854 (3) Angstrom and N-H...O 134degrees] to form (10 (3) over bar) sheets built from alternating R-2(2)(12) and R-6(6)(36) rings, both of which are centrosymmetric.

Original languageEnglish
Pages (from-to)o100-o102
Number of pages3
JournalActa Crystallographica Section C, Crystal Structure Communications
Volume58
Issue number2
DOIs
Publication statusPublished - Feb 2002

Fingerprint

Hydrogen Bonding
Names
Hydrogen
Hydrogen bonds
Molecules
nitroaniline
4-nitroaniline

Keywords

  • crystal

Cite this

Hydrogen bonding in C-substituted nitroanilines: sheets built from alternating R-2(2)(12) and R-6(6)(36) rings in 2-bromo-6-cyano-4-nitroaniline. / Glidewell, C ; Low, J N ; McWilliam, S A ; Skakle, Jan; Wardell, J L .

In: Acta Crystallographica Section C, Crystal Structure Communications, Vol. 58, No. 2, 02.2002, p. o100-o102.

Research output: Contribution to journal › Article

Glidewell, C, Low, JN, McWilliam, SA, Skakle, J & Wardell, JL 2002, 'Hydrogen bonding in C-substituted nitroanilines: sheets built from alternating R-2(2)(12) and R-6(6)(36) rings in 2-bromo-6-cyano-4-nitroaniline', Acta Crystallographica Section C, Crystal Structure Communications, vol. 58, no. 2, pp. o100-o102. https://doi.org/10.1107/S0108270101021485
Glidewell C, Low JN, McWilliam SA, Skakle J, Wardell JL. Hydrogen bonding in C-substituted nitroanilines: sheets built from alternating R-2(2)(12) and R-6(6)(36) rings in 2-bromo-6-cyano-4-nitroaniline. Acta Crystallographica Section C, Crystal Structure Communications. 2002 Feb;58(2):o100-o102. https://doi.org/10.1107/S0108270101021485
Glidewell, C ; Low, J N ; McWilliam, S A ; Skakle, Jan ; Wardell, J L . / Hydrogen bonding in C-substituted nitroanilines: sheets built from alternating R-2(2)(12) and R-6(6)(36) rings in 2-bromo-6-cyano-4-nitroaniline. In: Acta Crystallographica Section C, Crystal Structure Communications. 2002 ; Vol. 58, No. 2. pp. o100-o102.
@article{8a90d14125a04fc5b2a280738762c458,
title = "Hydrogen bonding in C-substituted nitroanilines: sheets built from alternating R-2(2)(12) and R-6(6)(36) rings in 2-bromo-6-cyano-4-nitroaniline",
abstract = "Molecules of the title compound (systematic name: 2-amino-3-bromo-5-nitrobenzonitrile), C7H4BrN3O2, are linked by N-H...N and N-H...O hydrogen bonds [H...N 2.19 Angstrom, N...N 3.019 (4) Angstrom and N-H...N 157degrees, and H...O 2.17 Angstrom, N...O 2.854 (3) Angstrom and N-H...O 134degrees] to form (10 (3) over bar) sheets built from alternating R-2(2)(12) and R-6(6)(36) rings, both of which are centrosymmetric.",
keywords = "crystal",
author = "C Glidewell and Low, {J N} and McWilliam, {S A} and Jan Skakle and Wardell, {J L}",
year = "2002",
month = "2",
doi = "10.1107/S0108270101021485",
language = "English",
volume = "58",
pages = "o100--o102",
journal = "Acta Crystallographica Section C, Crystal Structure Communications",
issn = "0108-2701",
publisher = "Wiley-Blackwell",
number = "2",

}

TY - JOUR

T1 - Hydrogen bonding in C-substituted nitroanilines: sheets built from alternating R-2(2)(12) and R-6(6)(36) rings in 2-bromo-6-cyano-4-nitroaniline

AU - Glidewell, C

AU - Low, J N

AU - McWilliam, S A

AU - Skakle, Jan

AU - Wardell, J L

PY - 2002/2

Y1 - 2002/2

N2 - Molecules of the title compound (systematic name: 2-amino-3-bromo-5-nitrobenzonitrile), C7H4BrN3O2, are linked by N-H...N and N-H...O hydrogen bonds [H...N 2.19 Angstrom, N...N 3.019 (4) Angstrom and N-H...N 157degrees, and H...O 2.17 Angstrom, N...O 2.854 (3) Angstrom and N-H...O 134degrees] to form (10 (3) over bar) sheets built from alternating R-2(2)(12) and R-6(6)(36) rings, both of which are centrosymmetric.

AB - Molecules of the title compound (systematic name: 2-amino-3-bromo-5-nitrobenzonitrile), C7H4BrN3O2, are linked by N-H...N and N-H...O hydrogen bonds [H...N 2.19 Angstrom, N...N 3.019 (4) Angstrom and N-H...N 157degrees, and H...O 2.17 Angstrom, N...O 2.854 (3) Angstrom and N-H...O 134degrees] to form (10 (3) over bar) sheets built from alternating R-2(2)(12) and R-6(6)(36) rings, both of which are centrosymmetric.

KW - crystal

U2 - 10.1107/S0108270101021485

DO - 10.1107/S0108270101021485

M3 - Article

VL - 58

SP - o100-o102

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

SN - 0108-2701

IS - 2

ER -

Access to Document