Hydrogen bonding in C-substituted nitroanilines: sheets built from alternating R-2(2)(12) and R-6(6)(36) rings in 2-bromo-6-cyano-4-nitroaniline

C Glidewell, J N Low, S A McWilliam, Jan Skakle, J L Wardell

Research output: Contribution to journal › Article

7 Citations (Scopus)

Abstract

Molecules of the title compound (systematic name: 2-amino-3-bromo-5-nitrobenzonitrile), C7H4BrN3O2, are linked by N-H...N and N-H...O hydrogen bonds [H...N 2.19 Angstrom, N...N 3.019 (4) Angstrom and N-H...N 157degrees, and H...O 2.17 Angstrom, N...O 2.854 (3) Angstrom and N-H...O 134degrees] to form (10 (3) over bar) sheets built from alternating R-2(2)(12) and R-6(6)(36) rings, both of which are centrosymmetric.

Original languageEnglish
Pages (from-to)o100-o102
Number of pages3
JournalActa Crystallographica Section C, Crystal Structure Communications
Volume58
Issue number2
DOIs
Publication statusPublished - Feb 2002

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Hydrogen Bonding
Names
Hydrogen
Hydrogen bonds
Molecules
nitroaniline
4-nitroaniline

Keywords

  • crystal

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Hydrogen bonding in C-substituted nitroanilines: sheets built from alternating R-2(2)(12) and R-6(6)(36) rings in 2-bromo-6-cyano-4-nitroaniline. / Glidewell, C ; Low, J N ; McWilliam, S A ; Skakle, Jan; Wardell, J L .

In: Acta Crystallographica Section C, Crystal Structure Communications, Vol. 58, No. 2, 02.2002, p. o100-o102.

Research output: Contribution to journal › Article

Glidewell, C, Low, JN, McWilliam, SA, Skakle, J & Wardell, JL 2002, 'Hydrogen bonding in C-substituted nitroanilines: sheets built from alternating R-2(2)(12) and R-6(6)(36) rings in 2-bromo-6-cyano-4-nitroaniline' Acta Crystallographica Section C, Crystal Structure Communications, vol. 58, no. 2, pp. o100-o102. https://doi.org/10.1107/S0108270101021485
Glidewell C, Low JN, McWilliam SA, Skakle J, Wardell JL. Hydrogen bonding in C-substituted nitroanilines: sheets built from alternating R-2(2)(12) and R-6(6)(36) rings in 2-bromo-6-cyano-4-nitroaniline. Acta Crystallographica Section C, Crystal Structure Communications. 2002 Feb;58(2):o100-o102. https://doi.org/10.1107/S0108270101021485
Glidewell, C ; Low, J N ; McWilliam, S A ; Skakle, Jan ; Wardell, J L . / Hydrogen bonding in C-substituted nitroanilines: sheets built from alternating R-2(2)(12) and R-6(6)(36) rings in 2-bromo-6-cyano-4-nitroaniline. In: Acta Crystallographica Section C, Crystal Structure Communications. 2002 ; Vol. 58, No. 2. pp. o100-o102.
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abstract = "Molecules of the title compound (systematic name: 2-amino-3-bromo-5-nitrobenzonitrile), C7H4BrN3O2, are linked by N-H...N and N-H...O hydrogen bonds [H...N 2.19 Angstrom, N...N 3.019 (4) Angstrom and N-H...N 157degrees, and H...O 2.17 Angstrom, N...O 2.854 (3) Angstrom and N-H...O 134degrees] to form (10 (3) over bar) sheets built from alternating R-2(2)(12) and R-6(6)(36) rings, both of which are centrosymmetric.",
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AB - Molecules of the title compound (systematic name: 2-amino-3-bromo-5-nitrobenzonitrile), C7H4BrN3O2, are linked by N-H...N and N-H...O hydrogen bonds [H...N 2.19 Angstrom, N...N 3.019 (4) Angstrom and N-H...N 157degrees, and H...O 2.17 Angstrom, N...O 2.854 (3) Angstrom and N-H...O 134degrees] to form (10 (3) over bar) sheets built from alternating R-2(2)(12) and R-6(6)(36) rings, both of which are centrosymmetric.

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