Hydrothermal synthesis and crystal structure of poly[bis- (μ3-3,4-diaminobenzoato) manganese], a layered coordination polymer

Muhammad Kaleem Khosa; Paul T. Wood; Simon M. Humphrey; William T. A. Harrison

doi:10.1107/S2056989020006805

Hydrothermal synthesis and crystal structure of poly[bis- (μ₃-3,4-diaminobenzoato) manganese], a layered coordination polymer

Muhammad Kaleem Khosa, Paul T. Wood, Simon M. Humphrey, William T. A. Harrison^* (Corresponding Author)

^*Corresponding author for this work

Chemistry

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Abstract

The hydrothermal synthesis and crystal structure of the title two-dimensional
coordination polymer, poly[bis(3-3,4-diaminobenzoato-3 N3,O,O0 )manganese(II)], [Mn(C7H7N2O2)2]n, are described. The Mn2+ cation (site symmetry 1) adopts a tetragonally elongated trans-MnN2O4 octahedral coordination geometry and the 3-N,O,O0 ligand (bonding from both carboxylate O atoms and the meta-N atom) links the metal ions into infinite (101) layers. The packing is consolidated by intra-layer N—HO and inter-layer N—HN hydrogen bonds. The structure of the title compound is compared with other complexes containing the C7H7N2O2 anion and those of the related M(C8H8NO2)2 (M = Mn, Co, Ni, Zn) family, where C8H8NO2 is the 3-amino-4-methylbenzoate anion.

Original language	English
Pages (from-to)	909-913
Number of pages	5
Journal	Acta Crystallographica Section E: Crystallographic Communications
Volume	76
Issue number	6
Early online date	22 May 2020
DOIs	https://doi.org/10.1107/S2056989020006805
Publication status	Published - Jun 2020

Keywords

manganese
ligand
layered structure
coordination polymer
crystal structure
Coordination polymer
Ligand
Layered structure
Crystal structure
Manganese

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Hydrothermal synthesis and crystal structure of poly[bis- (μ₃-3,4-diaminobenzoato) manganese], a layered coordination polymer. / Khosa, Muhammad Kaleem; Wood, Paul T.; Humphrey, Simon M. et al.

In: Acta Crystallographica Section E: Crystallographic Communications, Vol. 76, No. 6, 06.2020, p. 909-913.

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title = "Hydrothermal synthesis and crystal structure of poly[bis- (μ3-3,4-diaminobenzoato) manganese], a layered coordination polymer",

abstract = "The hydrothermal synthesis and crystal structure of the title two-dimensionalcoordination polymer, poly[bis(3-3,4-diaminobenzoato-3 N3,O,O0 )manganese(II)], [Mn(C7H7N2O2)2]n, are described. The Mn2+ cation (site symmetry 1) adopts a tetragonally elongated trans-MnN2O4 octahedral coordination geometry and the 3-N,O,O0 ligand (bonding from both carboxylate O atoms and the meta-N atom) links the metal ions into infinite (101) layers. The packing is consolidated by intra-layer N—HO and inter-layer N—HN hydrogen bonds. The structure of the title compound is compared with other complexes containing the C7H7N2O2 anion and those of the related M(C8H8NO2)2 (M = Mn, Co, Ni, Zn) family, where C8H8NO2 is the 3-amino-4-methylbenzoate anion.",

keywords = "manganese, ligand, layered structure, coordination polymer, crystal structure, Coordination polymer, Ligand, Layered structure, Crystal structure, Manganese",

author = "Khosa, {Muhammad Kaleem} and Wood, {Paul T.} and Humphrey, {Simon M.} and Harrison, {William T. A.}",

note = "Acknowledgements The EPSRC National Crystallography Service (University of Southampton) is thanked for the intensity data collection. Funding information We thank the Higher Education Commission of Pakistan (grant No. 1–3/PM-PDFP-II/2006/22) for financial support",

year = "2020",

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doi = "10.1107/S2056989020006805",

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T1 - Hydrothermal synthesis and crystal structure of poly[bis- (μ3-3,4-diaminobenzoato) manganese], a layered coordination polymer

AU - Khosa, Muhammad Kaleem

AU - Wood, Paul T.

AU - Humphrey, Simon M.

AU - Harrison, William T. A.

N1 - Acknowledgements The EPSRC National Crystallography Service (University of Southampton) is thanked for the intensity data collection. Funding information We thank the Higher Education Commission of Pakistan (grant No. 1–3/PM-PDFP-II/2006/22) for financial support

PY - 2020/6

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N2 - The hydrothermal synthesis and crystal structure of the title two-dimensionalcoordination polymer, poly[bis(3-3,4-diaminobenzoato-3 N3,O,O0 )manganese(II)], [Mn(C7H7N2O2)2]n, are described. The Mn2+ cation (site symmetry 1) adopts a tetragonally elongated trans-MnN2O4 octahedral coordination geometry and the 3-N,O,O0 ligand (bonding from both carboxylate O atoms and the meta-N atom) links the metal ions into infinite (101) layers. The packing is consolidated by intra-layer N—HO and inter-layer N—HN hydrogen bonds. The structure of the title compound is compared with other complexes containing the C7H7N2O2 anion and those of the related M(C8H8NO2)2 (M = Mn, Co, Ni, Zn) family, where C8H8NO2 is the 3-amino-4-methylbenzoate anion.

AB - The hydrothermal synthesis and crystal structure of the title two-dimensionalcoordination polymer, poly[bis(3-3,4-diaminobenzoato-3 N3,O,O0 )manganese(II)], [Mn(C7H7N2O2)2]n, are described. The Mn2+ cation (site symmetry 1) adopts a tetragonally elongated trans-MnN2O4 octahedral coordination geometry and the 3-N,O,O0 ligand (bonding from both carboxylate O atoms and the meta-N atom) links the metal ions into infinite (101) layers. The packing is consolidated by intra-layer N—HO and inter-layer N—HN hydrogen bonds. The structure of the title compound is compared with other complexes containing the C7H7N2O2 anion and those of the related M(C8H8NO2)2 (M = Mn, Co, Ni, Zn) family, where C8H8NO2 is the 3-amino-4-methylbenzoate anion.

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Hydrothermal synthesis and crystal structure of poly[bis- (μ₃-3,4-diaminobenzoato) manganese], a layered coordination polymer

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