Laurentian crustal recycling in the Ordovician Grampian Orogeny: Nd isotopic evidence from Western Ireland

Because magmatism associated with subduction is thought to be the principal source for continental crust generation, assessing the relative contribution of pre-existing (subducted and assimilated) continental material to arc magmatism in accreted arcs is important to understanding the origin of continental crust. We present a detailed Nd isotopic stratigraphy for volcanic and volcaniclastic formations from the South Mayo Trough, an accreted oceanic arc exposed in the western Irish Caledonides. These units span an arc-continent collision event, the Grampian (Taconic) Orogeny, in which an intra-oceanic island arc was accreted onto the passive continental margin of Laurentia starting at similar to 475 Ma (Arenig). The stratigraphy corresponding to pre-, syn- and post-collisional volcanism reveals a progression of epsilon(Nd(t)) from strongly positive values, consistent with melt derivation almost exclusively from oceanic mantle beneath the arc, to strongly negative values, indicating incorporation of continental material into the melt. Using epsilon(Nd(t)) values of meta-sediments that represent the Laurentian passive margin and accretionary prism, we are able to quantify the relative proportions of continent-derived melt at various stages of arc formation and accretion. Mass balance calculations show that mantle-derived magmatism contributes substantially to melt production during all stages of arc-continent collision, never accounting for less than 21 % of the total. This implies that a significant addition of new, rather than recycled, continental crust can accompany arc-continent collision and continental arc magmatism.