N,N′-[1,3-Phenyl-enebis(methyl-ene)]di-p-toluenesulfonamide

Ejaz, Islam Ullah Khan*, William Thomas Alexander Harrison, Rukhsana Anjum

*Corresponding author for this work

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

In the title compound, C 22H 24N 2O 4S 2, the dihedral angles between the central benzene ring and the pendant rings are 66.96 (13) and 69.37 (13)°. The torsion angles for the C-N-S-C fragments are-68.5 (3) and-72.6 (3)°. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds to generate infinite (001) sheets containing R 4 4(28) loops. A weak aromatic π-π stacking contact between one of the terminal benzene rings and its inversion-related partner is also observed [centroid-to-centroid separation = 3.796 (2) Å and slippage = 1.581 Å], as are two possible C-H⋯π contacts.

Original languageEnglish
Article numbero950
Number of pages8
JournalActa Crystallographica Section E: Structure Reports Online
VolumeE68
Early online dateApr 2012
DOIs
Publication statusPublished - Apr 2012

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Benzene
centroids
rings
Dihedral angle
benzene
Torsional stress
Hydrogen bonds
Crystals
torsion
dihedral angle
fragments
inversions
hydrogen bonds
crystals

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

Cite this

N,N′-[1,3-Phenyl-enebis(methyl-ene)]di-p-toluenesulfonamide. / Ejaz; Khan, Islam Ullah; Harrison, William Thomas Alexander; Anjum, Rukhsana.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. E68, o950, 04.2012.

Research output: Contribution to journalArticle

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