Polymeric diaqua(µ2-2,2'-bipyrimidinyl-k4N1,N1':N3,N3')-di-µ3-hydroxy-bis(5-benzene-1,3,5-tricarboxylato-k5O1:O2:O3:O3:O5)tetracobalt(II) dihydrate

M J Plater, M R S Foreman, R A Howie

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1 Citation (Scopus)

Abstract

The structure of the title compound, [Co-4 (C9H3O6)(2) (OH)(2) (C-8 H6N4)(H2O)(2)].2H(2)O, contains three separate species, namely the mu(5)-bridging C9H3O63- anion, the doubly chelating and therefore mu(2)-bridging C8H6N4 ligand (bipyrimidine, BPM), and the dihydrated diaquadihydroxy tetranuclear cationic cluster, [Co-4 (OH-)(2) (H2O)(2)](6+).2H(2)O, which lies on a crystallographic centre of symmetry, as does the BPM ligand with, in this case, the centre of symmetry coincident with the midpoint of the C-C bond joining the six-membered rings. Within the cation cluster, the Co atoms of one pair are five-coordinate and those of the other six-coordinate.

Original languageEnglish
Pages (from-to)m487-m489
Number of pages3
JournalActa Crystallographica Section C, Crystal Structure Communications
VolumeC58
DOIs
Publication statusPublished - 2002

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Benzene
Ligands
Chelation
Joining
Anions
Cations
Atoms
hydroxide ion

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@article{6967aa3196854a63b2ada02ac614f831,
title = "Polymeric diaqua(µ2-2,2'-bipyrimidinyl-k4N1,N1':N3,N3')-di-µ3-hydroxy-bis(5-benzene-1,3,5-tricarboxylato-k5O1:O2:O3:O3:O5)tetracobalt(II) dihydrate",
abstract = "The structure of the title compound, [Co-4 (C9H3O6)(2) (OH)(2) (C-8 H6N4)(H2O)(2)].2H(2)O, contains three separate species, namely the mu(5)-bridging C9H3O63- anion, the doubly chelating and therefore mu(2)-bridging C8H6N4 ligand (bipyrimidine, BPM), and the dihydrated diaquadihydroxy tetranuclear cationic cluster, [Co-4 (OH-)(2) (H2O)(2)](6+).2H(2)O, which lies on a crystallographic centre of symmetry, as does the BPM ligand with, in this case, the centre of symmetry coincident with the midpoint of the C-C bond joining the six-membered rings. Within the cation cluster, the Co atoms of one pair are five-coordinate and those of the other six-coordinate.",
author = "Plater, {M J} and Foreman, {M R S} and Howie, {R A}",
year = "2002",
doi = "10.1107/S0108270102014804",
language = "English",
volume = "C58",
pages = "m487--m489",
journal = "Acta Crystallographica Section C, Crystal Structure Communications",
issn = "0108-2701",
publisher = "Wiley-Blackwell",

}

TY - JOUR

T1 - Polymeric diaqua(µ2-2,2'-bipyrimidinyl-k4N1,N1':N3,N3')-di-µ3-hydroxy-bis(5-benzene-1,3,5-tricarboxylato-k5O1:O2:O3:O3:O5)tetracobalt(II) dihydrate

AU - Plater, M J

AU - Foreman, M R S

AU - Howie, R A

PY - 2002

Y1 - 2002

N2 - The structure of the title compound, [Co-4 (C9H3O6)(2) (OH)(2) (C-8 H6N4)(H2O)(2)].2H(2)O, contains three separate species, namely the mu(5)-bridging C9H3O63- anion, the doubly chelating and therefore mu(2)-bridging C8H6N4 ligand (bipyrimidine, BPM), and the dihydrated diaquadihydroxy tetranuclear cationic cluster, [Co-4 (OH-)(2) (H2O)(2)](6+).2H(2)O, which lies on a crystallographic centre of symmetry, as does the BPM ligand with, in this case, the centre of symmetry coincident with the midpoint of the C-C bond joining the six-membered rings. Within the cation cluster, the Co atoms of one pair are five-coordinate and those of the other six-coordinate.

AB - The structure of the title compound, [Co-4 (C9H3O6)(2) (OH)(2) (C-8 H6N4)(H2O)(2)].2H(2)O, contains three separate species, namely the mu(5)-bridging C9H3O63- anion, the doubly chelating and therefore mu(2)-bridging C8H6N4 ligand (bipyrimidine, BPM), and the dihydrated diaquadihydroxy tetranuclear cationic cluster, [Co-4 (OH-)(2) (H2O)(2)](6+).2H(2)O, which lies on a crystallographic centre of symmetry, as does the BPM ligand with, in this case, the centre of symmetry coincident with the midpoint of the C-C bond joining the six-membered rings. Within the cation cluster, the Co atoms of one pair are five-coordinate and those of the other six-coordinate.

U2 - 10.1107/S0108270102014804

DO - 10.1107/S0108270102014804

M3 - Article

VL - C58

SP - m487-m489

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

SN - 0108-2701

ER -