Pseudopyramidal Building Units in Mixed Inorganic/Organic Network Solids: Syntheses, Structures and Properties of a- and ß-ZnHPO3·N4C2H4

William Thomas Alexander Harrison, M. L. F. Phillips, J. Stanchfield, T. M. Nenoff

Research output: Contribution to journalArticle

93 Citations (Scopus)

Abstract

The syntheses, crystal structures, and some properties of alpha- and beta -ZnHPO3.N4C2H4 are reported. These polymorphic phases are the first organically templated hydrogen phosphites. They are built up from vertex-sharing HPO3 pseudopyramids and ZnO3N tetrahedra, where the Zn-N bond represents a direct link between zinc and the neutral 2-cyanoguanidine template. alpha -ZnHPO3.N4C2H4 is built up from infinite layers of vertex-sharing ZnO3N and HPO3 groups forming 4-rings and 8-rings. beta -ZnHPO3.N4C2H4 has strong one-dimensional character, with the polyhedral building units forming 4-ring ladders. Similarities and differences to related zinc phosphates are discussed. Crystal data: alpha -ZnHPO3.N4C2H4, monoclinic, P2(1)/c, a = 9.7718 (5) Angstrom, b = 8.2503 (4) Angstrom, c = 9.2491 (5) A, beta = 104.146 (1)degrees, Z = 4. beta -ZnHPO3.N4C2H4, monoclinic, C2/c, a = 14.5092 (9) Angstrom, b = 10.5464(6) Angstrom, 10.3342 (6) Angstrom, beta = 114.290 (1)degrees, Z = 8.

Original languageEnglish
Pages (from-to)895-899
Number of pages4
JournalInorganic Chemistry
Volume40
DOIs
Publication statusPublished - 2001

Keywords

  • HYDROTHERMAL SYNTHESES
  • TIN(II) PHOSPHATE
  • ZINC-PHOSPHATES
  • FRAMEWORKS
  • PHOSPHITES
  • CHANNELS

Cite this

Pseudopyramidal Building Units in Mixed Inorganic/Organic Network Solids: Syntheses, Structures and Properties of a- and ß-ZnHPO3·N4C2H4. / Harrison, William Thomas Alexander; Phillips, M. L. F.; Stanchfield, J.; Nenoff, T. M.

In: Inorganic Chemistry, Vol. 40, 2001, p. 895-899.

Research output: Contribution to journalArticle

@article{d4fa3780af3f4f09ba116f638d97960d,
title = "Pseudopyramidal Building Units in Mixed Inorganic/Organic Network Solids: Syntheses, Structures and Properties of a- and {\ss}-ZnHPO3·N4C2H4",
abstract = "The syntheses, crystal structures, and some properties of alpha- and beta -ZnHPO3.N4C2H4 are reported. These polymorphic phases are the first organically templated hydrogen phosphites. They are built up from vertex-sharing HPO3 pseudopyramids and ZnO3N tetrahedra, where the Zn-N bond represents a direct link between zinc and the neutral 2-cyanoguanidine template. alpha -ZnHPO3.N4C2H4 is built up from infinite layers of vertex-sharing ZnO3N and HPO3 groups forming 4-rings and 8-rings. beta -ZnHPO3.N4C2H4 has strong one-dimensional character, with the polyhedral building units forming 4-ring ladders. Similarities and differences to related zinc phosphates are discussed. Crystal data: alpha -ZnHPO3.N4C2H4, monoclinic, P2(1)/c, a = 9.7718 (5) Angstrom, b = 8.2503 (4) Angstrom, c = 9.2491 (5) A, beta = 104.146 (1)degrees, Z = 4. beta -ZnHPO3.N4C2H4, monoclinic, C2/c, a = 14.5092 (9) Angstrom, b = 10.5464(6) Angstrom, 10.3342 (6) Angstrom, beta = 114.290 (1)degrees, Z = 8.",
keywords = "HYDROTHERMAL SYNTHESES, TIN(II) PHOSPHATE, ZINC-PHOSPHATES, FRAMEWORKS, PHOSPHITES, CHANNELS",
author = "Harrison, {William Thomas Alexander} and Phillips, {M. L. F.} and J. Stanchfield and Nenoff, {T. M.}",
year = "2001",
doi = "10.1021/ic000723j",
language = "English",
volume = "40",
pages = "895--899",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",

}

TY - JOUR

T1 - Pseudopyramidal Building Units in Mixed Inorganic/Organic Network Solids: Syntheses, Structures and Properties of a- and ß-ZnHPO3·N4C2H4

AU - Harrison, William Thomas Alexander

AU - Phillips, M. L. F.

AU - Stanchfield, J.

AU - Nenoff, T. M.

PY - 2001

Y1 - 2001

N2 - The syntheses, crystal structures, and some properties of alpha- and beta -ZnHPO3.N4C2H4 are reported. These polymorphic phases are the first organically templated hydrogen phosphites. They are built up from vertex-sharing HPO3 pseudopyramids and ZnO3N tetrahedra, where the Zn-N bond represents a direct link between zinc and the neutral 2-cyanoguanidine template. alpha -ZnHPO3.N4C2H4 is built up from infinite layers of vertex-sharing ZnO3N and HPO3 groups forming 4-rings and 8-rings. beta -ZnHPO3.N4C2H4 has strong one-dimensional character, with the polyhedral building units forming 4-ring ladders. Similarities and differences to related zinc phosphates are discussed. Crystal data: alpha -ZnHPO3.N4C2H4, monoclinic, P2(1)/c, a = 9.7718 (5) Angstrom, b = 8.2503 (4) Angstrom, c = 9.2491 (5) A, beta = 104.146 (1)degrees, Z = 4. beta -ZnHPO3.N4C2H4, monoclinic, C2/c, a = 14.5092 (9) Angstrom, b = 10.5464(6) Angstrom, 10.3342 (6) Angstrom, beta = 114.290 (1)degrees, Z = 8.

AB - The syntheses, crystal structures, and some properties of alpha- and beta -ZnHPO3.N4C2H4 are reported. These polymorphic phases are the first organically templated hydrogen phosphites. They are built up from vertex-sharing HPO3 pseudopyramids and ZnO3N tetrahedra, where the Zn-N bond represents a direct link between zinc and the neutral 2-cyanoguanidine template. alpha -ZnHPO3.N4C2H4 is built up from infinite layers of vertex-sharing ZnO3N and HPO3 groups forming 4-rings and 8-rings. beta -ZnHPO3.N4C2H4 has strong one-dimensional character, with the polyhedral building units forming 4-ring ladders. Similarities and differences to related zinc phosphates are discussed. Crystal data: alpha -ZnHPO3.N4C2H4, monoclinic, P2(1)/c, a = 9.7718 (5) Angstrom, b = 8.2503 (4) Angstrom, c = 9.2491 (5) A, beta = 104.146 (1)degrees, Z = 4. beta -ZnHPO3.N4C2H4, monoclinic, C2/c, a = 14.5092 (9) Angstrom, b = 10.5464(6) Angstrom, 10.3342 (6) Angstrom, beta = 114.290 (1)degrees, Z = 8.

KW - HYDROTHERMAL SYNTHESES

KW - TIN(II) PHOSPHATE

KW - ZINC-PHOSPHATES

KW - FRAMEWORKS

KW - PHOSPHITES

KW - CHANNELS

U2 - 10.1021/ic000723j

DO - 10.1021/ic000723j

M3 - Article

VL - 40

SP - 895

EP - 899

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

ER -