Racemic cis-methoxobis(2-methyl-2-oxo-4H-pyran-4-olato)oxovanadium(V) redetermined at 120 K: hydrogen-bonded ribbons containing R (7), R (14) and R (18) rings

S. J. Kavitha, K. Panchanatheswaran, C. Glidewell

    Research output: Contribution to journalArticle

    1 Citation (Scopus)

    Abstract

    In the title compound, [V(CH3O)(C6H5O3)(2)O], the V - O bond lengths to the oxo and methoxo ligands are 1.593 ( 3) and 1.768 (3) angstrom, respectively, at 120 K; the V - O bond lengths trans to these two ligands are 2.246 ( 3) and 2.116 ( 3) angstrom. Molecules are linked by three C - H center dot center dot center dot O hydrogen bonds into complex ribbons containing three types of ring.

    Original languageEnglish
    Pages (from-to)M116-M118
    Number of pages3
    JournalActa Crystallographica Section C, Crystal Structure Communications
    Volume62
    Issue number62
    DOIs
    Publication statusPublished - 2006

    Keywords

    • X-RAY
    • BIS(MALTOLATO)OXOVANADIUM(IV)
    • DIFFRACTION
    • COMPLEXES

    Cite this

    Racemic cis-methoxobis(2-methyl-2-oxo-4H-pyran-4-olato)oxovanadium(V) redetermined at 120 K: hydrogen-bonded ribbons containing R (7), R (14) and R (18) rings. / Kavitha, S. J.; Panchanatheswaran, K.; Glidewell, C.

    In: Acta Crystallographica Section C, Crystal Structure Communications, Vol. 62, No. 62, 2006, p. M116-M118.

    Research output: Contribution to journalArticle

    @article{773d30d859ec48c69f575b484ff70b59,
    title = "Racemic cis-methoxobis(2-methyl-2-oxo-4H-pyran-4-olato)oxovanadium(V) redetermined at 120 K: hydrogen-bonded ribbons containing R (7), R (14) and R (18) rings",
    abstract = "In the title compound, [V(CH3O)(C6H5O3)(2)O], the V - O bond lengths to the oxo and methoxo ligands are 1.593 ( 3) and 1.768 (3) angstrom, respectively, at 120 K; the V - O bond lengths trans to these two ligands are 2.246 ( 3) and 2.116 ( 3) angstrom. Molecules are linked by three C - H center dot center dot center dot O hydrogen bonds into complex ribbons containing three types of ring.",
    keywords = "X-RAY, BIS(MALTOLATO)OXOVANADIUM(IV), DIFFRACTION, COMPLEXES",
    author = "Kavitha, {S. J.} and K. Panchanatheswaran and C. Glidewell",
    year = "2006",
    doi = "10.1107/S0108270106003404",
    language = "English",
    volume = "62",
    pages = "M116--M118",
    journal = "Acta Crystallographica Section C, Crystal Structure Communications",
    issn = "0108-2701",
    publisher = "Wiley-Blackwell",
    number = "62",

    }

    TY - JOUR

    T1 - Racemic cis-methoxobis(2-methyl-2-oxo-4H-pyran-4-olato)oxovanadium(V) redetermined at 120 K: hydrogen-bonded ribbons containing R (7), R (14) and R (18) rings

    AU - Kavitha, S. J.

    AU - Panchanatheswaran, K.

    AU - Glidewell, C.

    PY - 2006

    Y1 - 2006

    N2 - In the title compound, [V(CH3O)(C6H5O3)(2)O], the V - O bond lengths to the oxo and methoxo ligands are 1.593 ( 3) and 1.768 (3) angstrom, respectively, at 120 K; the V - O bond lengths trans to these two ligands are 2.246 ( 3) and 2.116 ( 3) angstrom. Molecules are linked by three C - H center dot center dot center dot O hydrogen bonds into complex ribbons containing three types of ring.

    AB - In the title compound, [V(CH3O)(C6H5O3)(2)O], the V - O bond lengths to the oxo and methoxo ligands are 1.593 ( 3) and 1.768 (3) angstrom, respectively, at 120 K; the V - O bond lengths trans to these two ligands are 2.246 ( 3) and 2.116 ( 3) angstrom. Molecules are linked by three C - H center dot center dot center dot O hydrogen bonds into complex ribbons containing three types of ring.

    KW - X-RAY

    KW - BIS(MALTOLATO)OXOVANADIUM(IV)

    KW - DIFFRACTION

    KW - COMPLEXES

    U2 - 10.1107/S0108270106003404

    DO - 10.1107/S0108270106003404

    M3 - Article

    VL - 62

    SP - M116-M118

    JO - Acta Crystallographica Section C, Crystal Structure Communications

    JF - Acta Crystallographica Section C, Crystal Structure Communications

    SN - 0108-2701

    IS - 62

    ER -