Racemic cis-methoxobis(2-methyl-2-oxo-4H-pyran-4-olato)oxovanadium(V) redetermined at 120 K: hydrogen-bonded ribbons containing R (7), R (14) and R (18) rings

S. J. Kavitha; K. Panchanatheswaran; C. Glidewell

doi:10.1107/S0108270106003404

Racemic cis-methoxobis(2-methyl-2-oxo-4H-pyran-4-olato)oxovanadium(V) redetermined at 120 K: hydrogen-bonded ribbons containing R (7), R (14) and R (18) rings

S. J. Kavitha, K. Panchanatheswaran, C. Glidewell

Research output: Contribution to journal › Article › peer-review

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Abstract

In the title compound, [V(CH3O)(C6H5O3)(2)O], the V - O bond lengths to the oxo and methoxo ligands are 1.593 ( 3) and 1.768 (3) angstrom, respectively, at 120 K; the V - O bond lengths trans to these two ligands are 2.246 ( 3) and 2.116 ( 3) angstrom. Molecules are linked by three C - H center dot center dot center dot O hydrogen bonds into complex ribbons containing three types of ring.

Original language	English
Pages (from-to)	M116-M118
Number of pages	3
Journal	Acta Crystallographica Section C, Crystal Structure Communications
Volume	62
Issue number	62
DOIs	https://doi.org/10.1107/S0108270106003404
Publication status	Published - 2006

Keywords

X-RAY
BIS(MALTOLATO)OXOVANADIUM(IV)
DIFFRACTION
COMPLEXES

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10.1107/S0108270106003404

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Racemic cis-methoxobis(2-methyl-2-oxo-4H-pyran-4-olato)oxovanadium(V) redetermined at 120 K: hydrogen-bonded ribbons containing R (7), R (14) and R (18) rings. / Kavitha, S. J.; Panchanatheswaran, K.; Glidewell, C.
In: Acta Crystallographica Section C, Crystal Structure Communications, Vol. 62, No. 62, 2006, p. M116-M118.

Research output: Contribution to journal › Article › peer-review

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title = "Racemic cis-methoxobis(2-methyl-2-oxo-4H-pyran-4-olato)oxovanadium(V) redetermined at 120 K: hydrogen-bonded ribbons containing R (7), R (14) and R (18) rings",

abstract = "In the title compound, [V(CH3O)(C6H5O3)(2)O], the V - O bond lengths to the oxo and methoxo ligands are 1.593 ( 3) and 1.768 (3) angstrom, respectively, at 120 K; the V - O bond lengths trans to these two ligands are 2.246 ( 3) and 2.116 ( 3) angstrom. Molecules are linked by three C - H center dot center dot center dot O hydrogen bonds into complex ribbons containing three types of ring.",

keywords = "X-RAY, BIS(MALTOLATO)OXOVANADIUM(IV), DIFFRACTION, COMPLEXES",

author = "Kavitha, {S. J.} and K. Panchanatheswaran and C. Glidewell",

year = "2006",

doi = "10.1107/S0108270106003404",

language = "English",

volume = "62",

pages = "M116--M118",

journal = "Acta Crystallographica Section C, Crystal Structure Communications",

issn = "0108-2701",

publisher = "Wiley-Blackwell ",

number = "62",

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TY - JOUR

T1 - Racemic cis-methoxobis(2-methyl-2-oxo-4H-pyran-4-olato)oxovanadium(V) redetermined at 120 K: hydrogen-bonded ribbons containing R (7), R (14) and R (18) rings

AU - Kavitha, S. J.

AU - Panchanatheswaran, K.

AU - Glidewell, C.

PY - 2006

Y1 - 2006

N2 - In the title compound, [V(CH3O)(C6H5O3)(2)O], the V - O bond lengths to the oxo and methoxo ligands are 1.593 ( 3) and 1.768 (3) angstrom, respectively, at 120 K; the V - O bond lengths trans to these two ligands are 2.246 ( 3) and 2.116 ( 3) angstrom. Molecules are linked by three C - H center dot center dot center dot O hydrogen bonds into complex ribbons containing three types of ring.

AB - In the title compound, [V(CH3O)(C6H5O3)(2)O], the V - O bond lengths to the oxo and methoxo ligands are 1.593 ( 3) and 1.768 (3) angstrom, respectively, at 120 K; the V - O bond lengths trans to these two ligands are 2.246 ( 3) and 2.116 ( 3) angstrom. Molecules are linked by three C - H center dot center dot center dot O hydrogen bonds into complex ribbons containing three types of ring.

KW - X-RAY

KW - BIS(MALTOLATO)OXOVANADIUM(IV)

KW - DIFFRACTION

KW - COMPLEXES

U2 - 10.1107/S0108270106003404

DO - 10.1107/S0108270106003404

M3 - Article

SN - 0108-2701

VL - 62

SP - M116-M118

JO - Acta Crystallographica Section C, Crystal Structure Communications

JF - Acta Crystallographica Section C, Crystal Structure Communications

IS - 62

ER -

Racemic cis-methoxobis(2-methyl-2-oxo-4H-pyran-4-olato)oxovanadium(V) redetermined at 120 K: hydrogen-bonded ribbons containing R (7), R (14) and R (18) rings

Abstract

Keywords

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