Reactions of secondary nitramines with tributylin hydride and tris (trimethylsilyl) silane

Research output: Contribution to journalComment/debate

Abstract

The reactions of secondary nitramines (N-nitroamines) with tributyitin hydride or tris(trimethylsilyl)silane have been investigated under free radical conditions. Reactions of nitramines with tributyltin radicals gave mostly the denitration products (secondary amines) whilst reactions with tris(trimethylsilyl)silyl radicals afforded almost exclusively nitrosamines (N-nitrosoamines).

Original languageEnglish
Pages (from-to)328-329
Number of pages2
JournalJournal of Chemical Research
Issue number8
Publication statusPublished - Aug 1995

Keywords

  • NITRO-COMPOUNDS
  • RADICALS
  • NITROALKANES

Cite this

Reactions of secondary nitramines with tributylin hydride and tris (trimethylsilyl) silane. / Imrie, Corrie Thomas.

In: Journal of Chemical Research, No. 8, 08.1995, p. 328-329.

Research output: Contribution to journalComment/debate

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abstract = "The reactions of secondary nitramines (N-nitroamines) with tributyitin hydride or tris(trimethylsilyl)silane have been investigated under free radical conditions. Reactions of nitramines with tributyltin radicals gave mostly the denitration products (secondary amines) whilst reactions with tris(trimethylsilyl)silyl radicals afforded almost exclusively nitrosamines (N-nitrosoamines).",
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N2 - The reactions of secondary nitramines (N-nitroamines) with tributyitin hydride or tris(trimethylsilyl)silane have been investigated under free radical conditions. Reactions of nitramines with tributyltin radicals gave mostly the denitration products (secondary amines) whilst reactions with tris(trimethylsilyl)silyl radicals afforded almost exclusively nitrosamines (N-nitrosoamines).

AB - The reactions of secondary nitramines (N-nitroamines) with tributyitin hydride or tris(trimethylsilyl)silane have been investigated under free radical conditions. Reactions of nitramines with tributyltin radicals gave mostly the denitration products (secondary amines) whilst reactions with tris(trimethylsilyl)silyl radicals afforded almost exclusively nitrosamines (N-nitrosoamines).

KW - NITRO-COMPOUNDS

KW - RADICALS

KW - NITROALKANES

M3 - Comment/debate

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JO - Journal of Chemical Research

JF - Journal of Chemical Research

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