Surface reactions of oxygen containing compounds on metal oxide (TiO2 and UO2) single crystals

Hicham Idriss

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

The surfaces of model metal oxides offer many fundamental examples where the outcome of a specific chemical reaction might be linked to the surface structure and local electronic properties. In this work the reaction of simple moleculessuch as ammonia, alcohols, carboxylic and amino acids is studied on two metal oxide single crystals: rutile TiO2(110) and (001) and fluorite UO2(111). Studies are conducted with XPS, TPD, and Plane Wave Density Functional Theory (DFT). The effect of surface structure is outlined by comparing the TiO2(110) rutile surface to those of TiO2(001), while the effect of surface point defects is mainly discussed in the case of stoichiometric and substoichiometric UO2(111).
Original languageEnglish
Title of host publicationModel Systems in Catalysis
Subtitle of host publicationSingle Crystals to Supported Enzyme Mimics
EditorsRobert Rioux
Place of PublicationNew York, NY, USA
PublisherSpringer Science+Business Media
Pages133-154
Number of pages22
ISBN (Print)0387980415 , 978-0387980416
DOIs
Publication statusPublished - 12 Nov 2010

Fingerprint

Surface reactions
Surface structure
Oxides
Metals
Single crystals
Oxygen
Fluorspar
Surface defects
Point defects
Temperature programmed desorption
Carboxylic Acids
Ammonia
Electronic properties
Density functional theory
Chemical reactions
X ray photoelectron spectroscopy
Alcohols
Amino Acids
titanium dioxide

Cite this

Idriss, H. (2010). Surface reactions of oxygen containing compounds on metal oxide (TiO2 and UO2) single crystals. In R. Rioux (Ed.), Model Systems in Catalysis: Single Crystals to Supported Enzyme Mimics (pp. 133-154). New York, NY, USA: Springer Science+Business Media. https://doi.org/10.1007/978-0-387-98049-2_7

Surface reactions of oxygen containing compounds on metal oxide (TiO2 and UO2) single crystals. / Idriss, Hicham.

Model Systems in Catalysis: Single Crystals to Supported Enzyme Mimics. ed. / Robert Rioux. New York, NY, USA : Springer Science+Business Media, 2010. p. 133-154.

Research output: Chapter in Book/Report/Conference proceedingChapter

Idriss, H 2010, Surface reactions of oxygen containing compounds on metal oxide (TiO2 and UO2) single crystals. in R Rioux (ed.), Model Systems in Catalysis: Single Crystals to Supported Enzyme Mimics. Springer Science+Business Media, New York, NY, USA, pp. 133-154. https://doi.org/10.1007/978-0-387-98049-2_7
Idriss H. Surface reactions of oxygen containing compounds on metal oxide (TiO2 and UO2) single crystals. In Rioux R, editor, Model Systems in Catalysis: Single Crystals to Supported Enzyme Mimics. New York, NY, USA: Springer Science+Business Media. 2010. p. 133-154 https://doi.org/10.1007/978-0-387-98049-2_7
Idriss, Hicham. / Surface reactions of oxygen containing compounds on metal oxide (TiO2 and UO2) single crystals. Model Systems in Catalysis: Single Crystals to Supported Enzyme Mimics. editor / Robert Rioux. New York, NY, USA : Springer Science+Business Media, 2010. pp. 133-154
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