Synthesis and characterisation of polymeric manganese and zinc 5-hydroxyisophthalates

Michael John Plater, M. R. S. J. Foreman, Robert Alan Howie, Janet Mabel Scott Skakle, S. A. McWilliam, E. Coronado, C. J. Gomez-Garcia

Research output: Contribution to journalArticle

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Abstract

The crystallisation of 5-hydroxyisophthalic acid with divalent Mn or with Mn or Zn and either 2,2-bipyridine (2,2-bipy) or pyridine-2-(1H-pyrazol-3-yl) gave solids of composition [Mn(C8H4O5)(H2O)(3)]. 2H(2)O (1), [Mn(C8H4O5)(2,2 ' -bipy)].H2O (2), [Mn-2(C8H4O5)(2)(C8H7N3)(2)].H2O (3) and [Zn(C8H4O5)(2,2 ' -bipy)] (4). Each compound has 1D co-ordinative chains that are connected by hydrogen bonds. Compounds 2-4 contain M2C2O4 rings with pseudo-chair geometries. The Mn atoms in 2 are coupled antiferromagnetically. (C) 2001 Elsevier Science Ltd. All rights reserved.

Original languageEnglish
Pages (from-to)2293-2303
Number of pages10
JournalPolyhedron
Volume20
DOIs
Publication statusPublished - 2001

Keywords

  • manganese
  • hydrothermal
  • co-ordination polymer
  • X-RAY STRUCTURE
  • MAGNETIC-PROPERTIES
  • CRYSTAL-STRUCTURE
  • COMPLEXES
  • CHAIN
  • OXIDATION
  • BEHAVIOR
  • BRIDGES

Cite this

Plater, M. J., Foreman, M. R. S. J., Howie, R. A., Skakle, J. M. S., McWilliam, S. A., Coronado, E., & Gomez-Garcia, C. J. (2001). Synthesis and characterisation of polymeric manganese and zinc 5-hydroxyisophthalates. Polyhedron, 20, 2293-2303. https://doi.org/10.1016/S0277-5387(01)00804-X

Synthesis and characterisation of polymeric manganese and zinc 5-hydroxyisophthalates. / Plater, Michael John; Foreman, M. R. S. J.; Howie, Robert Alan; Skakle, Janet Mabel Scott; McWilliam, S. A.; Coronado, E.; Gomez-Garcia, C. J.

In: Polyhedron, Vol. 20, 2001, p. 2293-2303.

Research output: Contribution to journalArticle

Plater, MJ, Foreman, MRSJ, Howie, RA, Skakle, JMS, McWilliam, SA, Coronado, E & Gomez-Garcia, CJ 2001, 'Synthesis and characterisation of polymeric manganese and zinc 5-hydroxyisophthalates', Polyhedron, vol. 20, pp. 2293-2303. https://doi.org/10.1016/S0277-5387(01)00804-X
Plater, Michael John ; Foreman, M. R. S. J. ; Howie, Robert Alan ; Skakle, Janet Mabel Scott ; McWilliam, S. A. ; Coronado, E. ; Gomez-Garcia, C. J. / Synthesis and characterisation of polymeric manganese and zinc 5-hydroxyisophthalates. In: Polyhedron. 2001 ; Vol. 20. pp. 2293-2303.
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AB - The crystallisation of 5-hydroxyisophthalic acid with divalent Mn or with Mn or Zn and either 2,2-bipyridine (2,2-bipy) or pyridine-2-(1H-pyrazol-3-yl) gave solids of composition [Mn(C8H4O5)(H2O)(3)]. 2H(2)O (1), [Mn(C8H4O5)(2,2 ' -bipy)].H2O (2), [Mn-2(C8H4O5)(2)(C8H7N3)(2)].H2O (3) and [Zn(C8H4O5)(2,2 ' -bipy)] (4). Each compound has 1D co-ordinative chains that are connected by hydrogen bonds. Compounds 2-4 contain M2C2O4 rings with pseudo-chair geometries. The Mn atoms in 2 are coupled antiferromagnetically. (C) 2001 Elsevier Science Ltd. All rights reserved.

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