Synthesis and characterization of novel chiral sulfonato–salen–manganese(III) complex in a zinc–aluminium LDH host

Samiran Bhattacharjee; Jim Anderson

doi:10.1039/b315325h

Synthesis and characterization of novel chiral sulfonato–salen–manganese(III) complex in a zinc–aluminium LDH host

Samiran Bhattacharjee, Jim Anderson

Chemistry

Research output: Contribution to journal › Article › peer-review

105 Citations (Scopus)

Abstract

A novel heterogeneous catalyst, [Zn2.15Al0.86(OH)6.02] [Mn]0.19[C6H5COO]0.48·2H2O, where {[Mn] = chiral sulfonato-salen-manganese(III) complex, Na2MnC20H22N2S2O12Cl, intercalated into ZnII–AlIII layered double hydroxide host}, has been synthesized and found to be an effective heterogeneous catalyst for the stereoselective epoxidation of R-(+)-limonene using molecular oxygen. The catalyst could be recycled without loss of performance.

Original language	English
Pages (from-to)	554-555
Number of pages	2
Journal	Chemical Communications
Issue number	5
Early online date	4 Feb 2004
DOIs	https://doi.org/10.1039/b315325h
Publication status	Published - 7 Mar 2004

Keywords

layered double hydroxides
enantioselective epoxidation
nonfunctionalized alkenes
oxygen
olefins
catalyst
clay

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10.1039/b315325h

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title = "Synthesis and characterization of novel chiral sulfonato–salen–manganese(III) complex in a zinc–aluminium LDH host",

abstract = "A novel heterogeneous catalyst, [Zn2.15Al0.86(OH)6.02] [Mn]0.19[C6H5COO]0.48·2H2O, where {[Mn] = chiral sulfonato-salen-manganese(III) complex, Na2MnC20H22N2S2O12Cl, intercalated into ZnII–AlIII layered double hydroxide host}, has been synthesized and found to be an effective heterogeneous catalyst for the stereoselective epoxidation of R-(+)-limonene using molecular oxygen. The catalyst could be recycled without loss of performance.",

keywords = "layered double hydroxides, enantioselective epoxidation, nonfunctionalized alkenes, oxygen, olefins, catalyst, clay",

author = "Samiran Bhattacharjee and Jim Anderson",

year = "2004",

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doi = "10.1039/b315325h",

language = "English",

pages = "554--555",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Synthesis and characterization of novel chiral sulfonato–salen–manganese(III) complex in a zinc–aluminium LDH host

AU - Bhattacharjee, Samiran

AU - Anderson, Jim

PY - 2004/3/7

Y1 - 2004/3/7

N2 - A novel heterogeneous catalyst, [Zn2.15Al0.86(OH)6.02] [Mn]0.19[C6H5COO]0.48·2H2O, where {[Mn] = chiral sulfonato-salen-manganese(III) complex, Na2MnC20H22N2S2O12Cl, intercalated into ZnII–AlIII layered double hydroxide host}, has been synthesized and found to be an effective heterogeneous catalyst for the stereoselective epoxidation of R-(+)-limonene using molecular oxygen. The catalyst could be recycled without loss of performance.

AB - A novel heterogeneous catalyst, [Zn2.15Al0.86(OH)6.02] [Mn]0.19[C6H5COO]0.48·2H2O, where {[Mn] = chiral sulfonato-salen-manganese(III) complex, Na2MnC20H22N2S2O12Cl, intercalated into ZnII–AlIII layered double hydroxide host}, has been synthesized and found to be an effective heterogeneous catalyst for the stereoselective epoxidation of R-(+)-limonene using molecular oxygen. The catalyst could be recycled without loss of performance.

KW - layered double hydroxides

KW - enantioselective epoxidation

KW - nonfunctionalized alkenes

KW - oxygen

KW - olefins

KW - catalyst

KW - clay

U2 - 10.1039/b315325h

DO - 10.1039/b315325h

M3 - Article

SN - 1359-7345

SP - 554

EP - 555

JO - Chemical Communications

JF - Chemical Communications

IS - 5

ER -

Synthesis and characterization of novel chiral sulfonato–salen–manganese(III) complex in a zinc–aluminium LDH host

Abstract

Keywords

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