Synthesis and crystal structure of [Cu2(NO3)4L2(BIPY)2(H2O)3].H2O (L = N,N'-bis(4-pyridylmethyl)

S. Buchan; Michael John Plater; M. R. S. J. Foreman; B. M. de Silva; Janet Mabel Scott Skakle; A. M. Z. Slawin

doi:10.1023/A:1015669012264

Synthesis and crystal structure of [Cu₂(NO₃)₄L₂(BIPY)₂(H₂O)₃].H₂O (L = N,N'-bis(4-pyridylmethyl)

S. Buchan, Michael John Plater, M. R. S. J. Foreman, B. M. de Silva, Janet Mabel Scott Skakle, A. M. Z. Slawin

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The synthesis and molecular structure of the title compound is reported. There are two different Cu atoms in separate chains which are linked to form double-stranded chains. Each Cu has a distorted octahedral coordination geometry. The structure has a triclinic space group P-1 with a = 11.0764(5), b = 15.9276(7), c = 18.2000(7) Angstrom, V = 3197.9(2) Angstrom(3), and Z = 2.

Original language	English
Pages (from-to)	5-10
Number of pages	5
Journal	Journal of Chemical Crystallography
Volume	32
Issue number	1
DOIs	https://doi.org/10.1023/A:1015669012264
Publication status	Published - 2002

Keywords

copper
crystallization
amide bond
crystal engineering
COMPLEX

Access to Document

10.1023/A:1015669012264

Cite this

@article{40ecb9a4ddc64ecb830ac15567098b47,

title = "Synthesis and crystal structure of [Cu2(NO3)4L2(BIPY)2(H2O)3].H2O (L = N,N'-bis(4-pyridylmethyl)",

abstract = "The synthesis and molecular structure of the title compound is reported. There are two different Cu atoms in separate chains which are linked to form double-stranded chains. Each Cu has a distorted octahedral coordination geometry. The structure has a triclinic space group P-1 with a = 11.0764(5), b = 15.9276(7), c = 18.2000(7) Angstrom, V = 3197.9(2) Angstrom(3), and Z = 2.",

keywords = "copper, crystallization, amide bond, crystal engineering, COMPLEX",

author = "S. Buchan and Plater, {Michael John} and Foreman, {M. R. S. J.} and {de Silva}, {B. M.} and Skakle, {Janet Mabel Scott} and Slawin, {A. M. Z.}",

year = "2002",

doi = "10.1023/A:1015669012264",

language = "English",

volume = "32",

pages = "5--10",

journal = "Journal of Chemical Crystallography",

issn = "1074-1542",

publisher = "Springer New York",

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TY - JOUR

T1 - Synthesis and crystal structure of [Cu2(NO3)4L2(BIPY)2(H2O)3].H2O (L = N,N'-bis(4-pyridylmethyl)

AU - Buchan, S.

AU - Plater, Michael John

AU - Foreman, M. R. S. J.

AU - de Silva, B. M.

AU - Skakle, Janet Mabel Scott

AU - Slawin, A. M. Z.

PY - 2002

Y1 - 2002

N2 - The synthesis and molecular structure of the title compound is reported. There are two different Cu atoms in separate chains which are linked to form double-stranded chains. Each Cu has a distorted octahedral coordination geometry. The structure has a triclinic space group P-1 with a = 11.0764(5), b = 15.9276(7), c = 18.2000(7) Angstrom, V = 3197.9(2) Angstrom(3), and Z = 2.

AB - The synthesis and molecular structure of the title compound is reported. There are two different Cu atoms in separate chains which are linked to form double-stranded chains. Each Cu has a distorted octahedral coordination geometry. The structure has a triclinic space group P-1 with a = 11.0764(5), b = 15.9276(7), c = 18.2000(7) Angstrom, V = 3197.9(2) Angstrom(3), and Z = 2.

KW - copper

KW - crystallization

KW - amide bond

KW - crystal engineering

KW - COMPLEX

U2 - 10.1023/A:1015669012264

DO - 10.1023/A:1015669012264

M3 - Article

SN - 1074-1542

VL - 32

SP - 5

EP - 10

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

IS - 1

ER -