Synthesis of Li3Cu2SbO6, a New Partially Ordered Rock Salt Structure

J. M S Skakle*, M. A. Castellanos R., S. Trujillo Tovar, A. R. West

*Corresponding author for this work

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

The new phase Li3Cu2SbO6, synthesised by solid state reaction at 1000°C, is monoclinic,a=5.4659(1),b=8.7272(2),c=9.7807(3) Å,β=95.080(2)°, space groupC2/c, and has a partially ordered rock salt structure related to the ordered structure of Li2TiO3by additional cation order: Ti sites are occupied by Cu and Sb in ordered fashion; Li sites contain Li/Cu in two sets, but with nonstatistical occupancy, and Li. Bond lengths show a Jahn-Teller elongation of CuO6octahedra consistent with magnetic susceptibility data that indicate paramagnetic Cu2+ions. Li3Cu2SbO6shows a low level of electronic conductivity.

Original languageEnglish
Pages (from-to)115-120
Number of pages6
JournalJournal of Solid State Chemistry
Volume131
Issue number1
DOIs
Publication statusPublished - 30 Jun 1997

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halites
Bond length
Solid state reactions
Magnetic susceptibility
elongation
Cations
Elongation
Salts
Positive ions
Rocks
Ions
solid state
magnetic permeability
cations
conductivity
synthesis
electronics
ions

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Synthesis of Li3Cu2SbO6, a New Partially Ordered Rock Salt Structure. / Skakle, J. M S; Castellanos R., M. A.; Tovar, S. Trujillo; West, A. R.

In: Journal of Solid State Chemistry, Vol. 131, No. 1, 30.06.1997, p. 115-120.

Research output: Contribution to journalArticle

Skakle, J. M S ; Castellanos R., M. A. ; Tovar, S. Trujillo ; West, A. R. / Synthesis of Li3Cu2SbO6, a New Partially Ordered Rock Salt Structure. In: Journal of Solid State Chemistry. 1997 ; Vol. 131, No. 1. pp. 115-120.
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