Synthesis of MXOY and related rings

M. R. S. J. Foreman, Robert Alan Howie, Michael John Plater, Janet Mabel Scott Skakle

Research output: Contribution to journalArticle

Abstract

By the hydrothermal reaction of lead (II) acetate with 2-benzonylbenzoic acid, colourless crystals of a hexanuclear lead carboxylate with bridging oxide ligands was obtained. The structure of the molecule could be described as being like a tennis ball of lead atoms at the centre of a soccer ball of carboxylate ligands. For clarity the carboxylate and oxide ligands have been omitted.

[GRAPHICS]

Crystal structures of other lead (II) carboxylates, which are polymeric, have been obtained.

Original languageEnglish
Pages (from-to)621-624
Number of pages3
JournalPhosphorus, Sulfur and SIlicon and the Related Elements
Volume168
Publication statusPublished - 2001

Cite this

Synthesis of MXOY and related rings. / Foreman, M. R. S. J.; Howie, Robert Alan; Plater, Michael John; Skakle, Janet Mabel Scott.

In: Phosphorus, Sulfur and SIlicon and the Related Elements, Vol. 168, 2001, p. 621-624.

Research output: Contribution to journalArticle

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AU - Howie, Robert Alan

AU - Plater, Michael John

AU - Skakle, Janet Mabel Scott

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N2 - By the hydrothermal reaction of lead (II) acetate with 2-benzonylbenzoic acid, colourless crystals of a hexanuclear lead carboxylate with bridging oxide ligands was obtained. The structure of the molecule could be described as being like a tennis ball of lead atoms at the centre of a soccer ball of carboxylate ligands. For clarity the carboxylate and oxide ligands have been omitted.[GRAPHICS]Crystal structures of other lead (II) carboxylates, which are polymeric, have been obtained.

AB - By the hydrothermal reaction of lead (II) acetate with 2-benzonylbenzoic acid, colourless crystals of a hexanuclear lead carboxylate with bridging oxide ligands was obtained. The structure of the molecule could be described as being like a tennis ball of lead atoms at the centre of a soccer ball of carboxylate ligands. For clarity the carboxylate and oxide ligands have been omitted.[GRAPHICS]Crystal structures of other lead (II) carboxylates, which are polymeric, have been obtained.

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JO - Phosphorus, Sulfur and SIlicon and the Related Elements

JF - Phosphorus, Sulfur and SIlicon and the Related Elements

SN - 1042-6507

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