The consistent hexameric paddle-wheel crystallisation motif of a family of 2,4-bis(n-alkylamino)nitrobenzenes: Alkyl = pentyl, hexyl, heptyl and octyl

M. John Plater; William T.A. Harrison; Laura M. Machado De Los Toyos; Lewis Hendry

doi:10.3184/174751917X14902201357356

The consistent hexameric paddle-wheel crystallisation motif of a family of 2,4-bis(n-alkylamino)nitrobenzenes: Alkyl = pentyl, hexyl, heptyl and octyl

M. John Plater^*, William T.A. Harrison, Laura M. Machado De Los Toyos, Lewis Hendry

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

10 Downloads (Pure)

Abstract

Three examples of 2,4-bis(n-alkylamino)nitrobenzenes have been crystallised (alkyl = pentyl, hexyl and heptyl) and the single crystal structures were determined. The three structures are similar and adopt a cyclic hydrogen bonded hexameric motif. n-Octyl alkyl chains prevented a crystal structure determination owing to disorder.

Original language	English
Pages (from-to)	235-238
Number of pages	4
Journal	Journal of Chemical Research
Volume	41
Issue number	4
Early online date	28 Mar 2017
DOIs	https://doi.org/10.3184/174751917X14902201357356
Publication status	Published - 1 Apr 2017

Keywords

2,4-bis(alkylamino)nitrobenzenes
Crystallisation
Hexameric
Hydrogen bond
Porous
Supramolecular

Access to Document

10.3184/174751917X14902201357356Licence: Unspecified

Accepted Manuscript
This is an Accepted Manuscript of an article published by Science Reviews 2000 Ltd in Journal of Chemical Research on 28/03/2017, available online: https://doi.org/10.3184/174751917X14902201357356
Accepted author manuscript, 612 KBLicence: Unspecified

Cite this

The consistent hexameric paddle-wheel crystallisation motif of a family of 2,4-bis(n-alkylamino)nitrobenzenes : Alkyl = pentyl, hexyl, heptyl and octyl. / Plater, M. John ; Harrison, William T.A.; Machado De Los Toyos, Laura M. et al.

In: Journal of Chemical Research, Vol. 41, No. 4, 01.04.2017, p. 235-238.

Research output: Contribution to journal › Article › peer-review

@article{69522a5f66244ef2b7bb23bf182af30a,

title = "The consistent hexameric paddle-wheel crystallisation motif of a family of 2,4-bis(n-alkylamino)nitrobenzenes: Alkyl = pentyl, hexyl, heptyl and octyl",

abstract = "Three examples of 2,4-bis(n-alkylamino)nitrobenzenes have been crystallised (alkyl = pentyl, hexyl and heptyl) and the single crystal structures were determined. The three structures are similar and adopt a cyclic hydrogen bonded hexameric motif. n-Octyl alkyl chains prevented a crystal structure determination owing to disorder.",

keywords = "2,4-bis(alkylamino)nitrobenzenes, Crystallisation, Hexameric, Hydrogen bond, Porous, Supramolecular",

author = "Plater, {M. John} and Harrison, {William T.A.} and {Machado De Los Toyos}, {Laura M.} and Lewis Hendry",

note = "We thank the EPSRC National Mass Spectrometry Service (University of Swansea) for the mass spectrometry data and the EPSRC National Crystallography Service (University of Southampton) for the X-ray intensity data collections. ",

year = "2017",

month = apr,

day = "1",

doi = "10.3184/174751917X14902201357356",

language = "English",

volume = "41",

pages = "235--238",

journal = "Journal of Chemical Research",

issn = "0308-2342",

publisher = "Science Reviews Ltd",

number = "4",

}

TY - JOUR

T1 - The consistent hexameric paddle-wheel crystallisation motif of a family of 2,4-bis(n-alkylamino)nitrobenzenes

T2 - Alkyl = pentyl, hexyl, heptyl and octyl

AU - Plater, M. John

AU - Harrison, William T.A.

AU - Machado De Los Toyos, Laura M.

AU - Hendry, Lewis

N1 - We thank the EPSRC National Mass Spectrometry Service (University of Swansea) for the mass spectrometry data and the EPSRC National Crystallography Service (University of Southampton) for the X-ray intensity data collections.

PY - 2017/4/1

Y1 - 2017/4/1

N2 - Three examples of 2,4-bis(n-alkylamino)nitrobenzenes have been crystallised (alkyl = pentyl, hexyl and heptyl) and the single crystal structures were determined. The three structures are similar and adopt a cyclic hydrogen bonded hexameric motif. n-Octyl alkyl chains prevented a crystal structure determination owing to disorder.

AB - Three examples of 2,4-bis(n-alkylamino)nitrobenzenes have been crystallised (alkyl = pentyl, hexyl and heptyl) and the single crystal structures were determined. The three structures are similar and adopt a cyclic hydrogen bonded hexameric motif. n-Octyl alkyl chains prevented a crystal structure determination owing to disorder.

KW - 2,4-bis(alkylamino)nitrobenzenes

KW - Crystallisation

KW - Hexameric

KW - Hydrogen bond

KW - Porous

KW - Supramolecular

UR - http://www.scopus.com/inward/record.url?scp=85020775084&partnerID=8YFLogxK

U2 - 10.3184/174751917X14902201357356

DO - 10.3184/174751917X14902201357356

M3 - Article

AN - SCOPUS:85020775084

VL - 41

SP - 235

EP - 238

JO - Journal of Chemical Research

JF - Journal of Chemical Research

SN - 0308-2342

IS - 4

ER -

The consistent hexameric paddle-wheel crystallisation motif of a family of 2,4-bis(n-alkylamino)nitrobenzenes: Alkyl = pentyl, hexyl, heptyl and octyl

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this