Variations on the (3,4)-Net Motif in Organo-Zincophosphite Chemistry: Synthesis and Structures of (CN3H6)2·Zn3(HPO3)4·H2O and H3N(CH2)3NH3·Zn3(HPO3)4·H2O

M. L. F. Phillips, T. M. Nenoff, C. T. Thompson, William Thomas Alexander Harrison

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Abstract

The solution-mediated syntheses and single-crystal structures of (CN3H6)(2) . Zn-3(HPO3)(4) . H2O (I) an H3N(CH2)(3)NH3 . Zn-3(HPO3)(4) . H2O (II) are reported. These phases contain networks of vertex-sharing ZnO4 tetrahedra and HPO3 pseudopyramids accompanied by organic cations and water molecules. Despite their similar formulae, these phases adopt different crystal structures, in terms of three-dimensional and two-dimensional ZnO4\HPO3 networks, for I and II, respectively. Their similarities and differences to other zinc phosphites and phosphates are briefly discussed. Crystal data: (CN3H6)(2) . Zn-3(HPO3)(4) . H2O, M-r = 654.23, triclinic, P (1) over bar (No. 2), a = 7.5121 (3) Angstrom, b = 8.9927 (4) Angstrom, c = 15.1530 (6) Angstrom, alpha = 90.256 (1)degrees, beta = 93.391 (1)degrees, gamma = 111.091 (1)degrees, V = 953.04 (7) Angstrom(3) Z = 2, R(F) = 0.048, wR(F-2) = 0.121. H3N(CH2)(3)NH3 . Zn-3(HPO3)(4) . H2O, M-r = 610.22, monoclinic, C2/c (No. 15), a = 8.9310 (4) Angstrom b = 14.4308 (6) Angstrom, c = 14.3669 (6) Angstrom, beta = 104.624 (1)degrees, V = 1791.64 (13) Angstrom(3), Z = 4, R(F) = 0.033, wR(F-2) = 0.087. (C) 2002 Elsevier Science (USA).

Original languageEnglish
Pages (from-to)337-343
Number of pages6
JournalJournal of Solid State Chemistry
Volume167
DOIs
Publication statusPublished - 2002

Keywords

  • HPO3 PSEUDO PYRAMIDS
  • ZINC PHOSPHATE
  • BUILT-UP
  • ZNO4 TETRAHEDRA
  • DENSITY

Cite this

@article{8c9a5bcdbaf14dbfb9428d51459d9618,
title = "Variations on the (3,4)-Net Motif in Organo-Zincophosphite Chemistry: Synthesis and Structures of (CN3H6)2·Zn3(HPO3)4·H2O and H3N(CH2)3NH3·Zn3(HPO3)4·H2O",
abstract = "The solution-mediated syntheses and single-crystal structures of (CN3H6)(2) . Zn-3(HPO3)(4) . H2O (I) an H3N(CH2)(3)NH3 . Zn-3(HPO3)(4) . H2O (II) are reported. These phases contain networks of vertex-sharing ZnO4 tetrahedra and HPO3 pseudopyramids accompanied by organic cations and water molecules. Despite their similar formulae, these phases adopt different crystal structures, in terms of three-dimensional and two-dimensional ZnO4\HPO3 networks, for I and II, respectively. Their similarities and differences to other zinc phosphites and phosphates are briefly discussed. Crystal data: (CN3H6)(2) . Zn-3(HPO3)(4) . H2O, M-r = 654.23, triclinic, P (1) over bar (No. 2), a = 7.5121 (3) Angstrom, b = 8.9927 (4) Angstrom, c = 15.1530 (6) Angstrom, alpha = 90.256 (1)degrees, beta = 93.391 (1)degrees, gamma = 111.091 (1)degrees, V = 953.04 (7) Angstrom(3) Z = 2, R(F) = 0.048, wR(F-2) = 0.121. H3N(CH2)(3)NH3 . Zn-3(HPO3)(4) . H2O, M-r = 610.22, monoclinic, C2/c (No. 15), a = 8.9310 (4) Angstrom b = 14.4308 (6) Angstrom, c = 14.3669 (6) Angstrom, beta = 104.624 (1)degrees, V = 1791.64 (13) Angstrom(3), Z = 4, R(F) = 0.033, wR(F-2) = 0.087. (C) 2002 Elsevier Science (USA).",
keywords = "HPO3 PSEUDO PYRAMIDS, ZINC PHOSPHATE, BUILT-UP, ZNO4 TETRAHEDRA, DENSITY",
author = "Phillips, {M. L. F.} and Nenoff, {T. M.} and Thompson, {C. T.} and Harrison, {William Thomas Alexander}",
year = "2002",
doi = "10.1006/jssc.2002.9539",
language = "English",
volume = "167",
pages = "337--343",
journal = "Journal of Solid State Chemistry",
issn = "0022-4596",
publisher = "ACADEMIC PRESS INC ELSEVIER SCIENCE",

}

TY - JOUR

T1 - Variations on the (3,4)-Net Motif in Organo-Zincophosphite Chemistry: Synthesis and Structures of (CN3H6)2·Zn3(HPO3)4·H2O and H3N(CH2)3NH3·Zn3(HPO3)4·H2O

AU - Phillips, M. L. F.

AU - Nenoff, T. M.

AU - Thompson, C. T.

AU - Harrison, William Thomas Alexander

PY - 2002

Y1 - 2002

N2 - The solution-mediated syntheses and single-crystal structures of (CN3H6)(2) . Zn-3(HPO3)(4) . H2O (I) an H3N(CH2)(3)NH3 . Zn-3(HPO3)(4) . H2O (II) are reported. These phases contain networks of vertex-sharing ZnO4 tetrahedra and HPO3 pseudopyramids accompanied by organic cations and water molecules. Despite their similar formulae, these phases adopt different crystal structures, in terms of three-dimensional and two-dimensional ZnO4\HPO3 networks, for I and II, respectively. Their similarities and differences to other zinc phosphites and phosphates are briefly discussed. Crystal data: (CN3H6)(2) . Zn-3(HPO3)(4) . H2O, M-r = 654.23, triclinic, P (1) over bar (No. 2), a = 7.5121 (3) Angstrom, b = 8.9927 (4) Angstrom, c = 15.1530 (6) Angstrom, alpha = 90.256 (1)degrees, beta = 93.391 (1)degrees, gamma = 111.091 (1)degrees, V = 953.04 (7) Angstrom(3) Z = 2, R(F) = 0.048, wR(F-2) = 0.121. H3N(CH2)(3)NH3 . Zn-3(HPO3)(4) . H2O, M-r = 610.22, monoclinic, C2/c (No. 15), a = 8.9310 (4) Angstrom b = 14.4308 (6) Angstrom, c = 14.3669 (6) Angstrom, beta = 104.624 (1)degrees, V = 1791.64 (13) Angstrom(3), Z = 4, R(F) = 0.033, wR(F-2) = 0.087. (C) 2002 Elsevier Science (USA).

AB - The solution-mediated syntheses and single-crystal structures of (CN3H6)(2) . Zn-3(HPO3)(4) . H2O (I) an H3N(CH2)(3)NH3 . Zn-3(HPO3)(4) . H2O (II) are reported. These phases contain networks of vertex-sharing ZnO4 tetrahedra and HPO3 pseudopyramids accompanied by organic cations and water molecules. Despite their similar formulae, these phases adopt different crystal structures, in terms of three-dimensional and two-dimensional ZnO4\HPO3 networks, for I and II, respectively. Their similarities and differences to other zinc phosphites and phosphates are briefly discussed. Crystal data: (CN3H6)(2) . Zn-3(HPO3)(4) . H2O, M-r = 654.23, triclinic, P (1) over bar (No. 2), a = 7.5121 (3) Angstrom, b = 8.9927 (4) Angstrom, c = 15.1530 (6) Angstrom, alpha = 90.256 (1)degrees, beta = 93.391 (1)degrees, gamma = 111.091 (1)degrees, V = 953.04 (7) Angstrom(3) Z = 2, R(F) = 0.048, wR(F-2) = 0.121. H3N(CH2)(3)NH3 . Zn-3(HPO3)(4) . H2O, M-r = 610.22, monoclinic, C2/c (No. 15), a = 8.9310 (4) Angstrom b = 14.4308 (6) Angstrom, c = 14.3669 (6) Angstrom, beta = 104.624 (1)degrees, V = 1791.64 (13) Angstrom(3), Z = 4, R(F) = 0.033, wR(F-2) = 0.087. (C) 2002 Elsevier Science (USA).

KW - HPO3 PSEUDO PYRAMIDS

KW - ZINC PHOSPHATE

KW - BUILT-UP

KW - ZNO4 TETRAHEDRA

KW - DENSITY

U2 - 10.1006/jssc.2002.9539

DO - 10.1006/jssc.2002.9539

M3 - Article

VL - 167

SP - 337

EP - 343

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

SN - 0022-4596

ER -