Volumetric properties of (piperidine + water) binary system: measurements and modeling

Waheed Afzal, Alain Valtz, Christophe Coquelet, Dominique Richon

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

Densities of pure piperidine (CAS No.: 110-89-4) and of its mixtures with water have been measured over the whole range of compositions at temperatures from 283.15 K to 347.15 K using Anton Paar™ digital vibrating tube densimeter. The density of this system has been found increasing with mass fraction of water. Excess molar volumes have been calculated using the measured experimental densities and correlated using the Redlich–Kister equation. Redlich–Kister equation parameters have been adjusted on experimental data. In addition, partial molar volumes and partial excess molar volumes at infinite dilution have been calculated for each component.
Original languageEnglish
Pages (from-to)47-53
Number of pages7
JournalThe Journal of Chemical Thermodynamics
Volume40
Issue number1
DOIs
Publication statusPublished - Jan 2008

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