Water denitration over a Pd-Sn/Al2O3 catalyst

J  Sa; D  Gasparovicova; K  Hayek; E  Halwax; J A  Anderson; H  Vinek

doi:10.1007/s10562-005-8692-7

Water denitration over a Pd-Sn/Al2O3 catalyst

J Sa, D Gasparovicova, K Hayek, E Halwax, J A Anderson, H Vinek

Chemistry

Research output: Contribution to journal › Article

50 Citations (Scopus)

Abstract

Bimetallic Pd-Sn catalysts were synthesized by incipient-wetness impregnation of the metals on alumina and employed for the reduction of nitrates from aqueous solutions. The catalysts were characterized by FTIR spectroscopy of adsorbed CO, X-ray diffraction (XRD), transmission electron microscopy (TEM), and H-2 chemisorption. The influence of the metal ratio was evaluated in reaction measurements. The bimetallic Pd-Sn catalysts exhibited high selectivity for nitrate removal forming less NO2- and NH4+ than the Pd-Cu catalysts.

Original language	English
Pages (from-to)	209-217
Number of pages	9
Journal	Catalysis Letters
Volume	105
DOIs	https://doi.org/10.1007/s10562-005-8692-7
Publication status	Published - 2005

Keywords

Pd-Sn/Al2O3
nitrate hydrogenation
XRD
FTIR using CO and TEM
PD-CU CATALYSTS
DRINKING-WATER
SELECTIVE HYDROGENATION
NITRATE REDUCTION
CARBON-MONOXIDE
TIN CATALYSTS
PALLADIUM-TIN
REMOVAL
NITRITE
PLATINUM

Access to Document

10.1007/s10562-005-8692-7

Cite this

@article{1e178d33d9f849b384c48ef66c3f5c4c,

title = "Water denitration over a Pd-Sn/Al2O3 catalyst",

abstract = "Bimetallic Pd-Sn catalysts were synthesized by incipient-wetness impregnation of the metals on alumina and employed for the reduction of nitrates from aqueous solutions. The catalysts were characterized by FTIR spectroscopy of adsorbed CO, X-ray diffraction (XRD), transmission electron microscopy (TEM), and H-2 chemisorption. The influence of the metal ratio was evaluated in reaction measurements. The bimetallic Pd-Sn catalysts exhibited high selectivity for nitrate removal forming less NO2- and NH4+ than the Pd-Cu catalysts.",

keywords = "Pd-Sn/Al2O3, nitrate hydrogenation, XRD, FTIR using CO and TEM, PD-CU CATALYSTS, DRINKING-WATER, SELECTIVE HYDROGENATION, NITRATE REDUCTION, CARBON-MONOXIDE, TIN CATALYSTS, PALLADIUM-TIN, REMOVAL, NITRITE, PLATINUM",

author = "J Sa and D Gasparovicova and K Hayek and E Halwax and Anderson, {J A} and H Vinek",

year = "2005",

doi = "10.1007/s10562-005-8692-7",

language = "English",

volume = "105",

pages = "209--217",

journal = "Catalysis Letters",

issn = "1011-372X",

publisher = "Springer Netherlands",

}

TY - JOUR

T1 - Water denitration over a Pd-Sn/Al2O3 catalyst

AU - Sa, J

AU - Gasparovicova, D

AU - Hayek, K

AU - Halwax, E

AU - Anderson, J A

AU - Vinek, H

PY - 2005

Y1 - 2005

N2 - Bimetallic Pd-Sn catalysts were synthesized by incipient-wetness impregnation of the metals on alumina and employed for the reduction of nitrates from aqueous solutions. The catalysts were characterized by FTIR spectroscopy of adsorbed CO, X-ray diffraction (XRD), transmission electron microscopy (TEM), and H-2 chemisorption. The influence of the metal ratio was evaluated in reaction measurements. The bimetallic Pd-Sn catalysts exhibited high selectivity for nitrate removal forming less NO2- and NH4+ than the Pd-Cu catalysts.

AB - Bimetallic Pd-Sn catalysts were synthesized by incipient-wetness impregnation of the metals on alumina and employed for the reduction of nitrates from aqueous solutions. The catalysts were characterized by FTIR spectroscopy of adsorbed CO, X-ray diffraction (XRD), transmission electron microscopy (TEM), and H-2 chemisorption. The influence of the metal ratio was evaluated in reaction measurements. The bimetallic Pd-Sn catalysts exhibited high selectivity for nitrate removal forming less NO2- and NH4+ than the Pd-Cu catalysts.

KW - Pd-Sn/Al2O3

KW - nitrate hydrogenation

KW - XRD

KW - FTIR using CO and TEM

KW - PD-CU CATALYSTS

KW - DRINKING-WATER

KW - SELECTIVE HYDROGENATION

KW - NITRATE REDUCTION

KW - CARBON-MONOXIDE

KW - TIN CATALYSTS

KW - PALLADIUM-TIN

KW - REMOVAL

KW - NITRITE

KW - PLATINUM

U2 - 10.1007/s10562-005-8692-7

DO - 10.1007/s10562-005-8692-7

M3 - Article

SN - 1011-372X

VL - 105

SP - 209

EP - 217

JO - Catalysis Letters

JF - Catalysis Letters

ER -

Water denitration over a Pd-Sn/Al2O3 catalyst

Abstract

Keywords

Access to Document

Fingerprint

Cite this