Water-in-salt environment reduces the overpotential for reduction of of CO2 to CO2: in ionic liquid/water mixtures

We report a combined computational and experimental work aimed at estimating
the equilibrium potential for the electroreduction of CO2 to CO2-(widely accepted to be the first and overpotential-determining step) and at throwing new light on the reason behind the lower overpotentials for CO2 reduction in imidazolium-based ionic liquid/water mixtures. First, we obtained an eighty-picosecond ab-initio molecular dynamics trajectory of the CO2 solvation
structures in an 18% EMIM-BF4/water mixture, which delivered no evidence of interaction between EMIM+ and CO2. . Second, using the Fc+/Fc couple as the non-aqueous reference, we calculated the equilibrium potential of the CO2/CO2
-couple in the mixture and aligned it with the aqueous SHE scale, proving that the equilibrium potential of CO2/CO2-in the mixture is about 0.3 V less negative than in the aqueous medium. We then looked for the origin of this catalytic effect, by comparing the computed vibrational spectra with experimental FTIR spectra. This revealed the presence of two water populations in the mixture, namely, bulk-like water and water in the vicinity of EMIM-BF4. Finally, we compared the hydrogen bonding interactions between the CO2
-radical and H2O molecules in water and in the mixture, which showed that stabilization of CO2- by water molecules in the EMIM-BF4/water mixture is stronger than in the aqueous medium. This suggests that water in EMIM-BF4/water mixtures could be responsible for the low overpotentials reported in this kind of electrolytes.